Bond-forming and-breaking reactions at sulfur (IV): sulfoxides, sulfonium salts, sulfur ylides, and sulfinate salts

D Kaiser, I Klose, R Oost, J Neuhaus… - Chemical …, 2019 - ACS Publications
Organosulfur compounds have long played a vital role in organic chemistry and in the
development of novel chemical structures and architectures. Prominent among these …

Visible‐light photocatalysis: does it make a difference in organic synthesis?

L Marzo, SK Pagire, O Reiser… - Angewandte Chemie …, 2018 - Wiley Online Library
Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …

Photokatalyse mit sichtbarem Licht: Welche Bedeutung hat sie für die organische Synthese?

L Marzo, SK Pagire, O Reiser, B König - Angewandte Chemie, 2018 - Wiley Online Library
Abstract Die Photokatalyse mit sichtbarem Licht hat sich im letzten Jahrzehnt zu einer breit
angewandten Methode in der organischen Synthese entwickelt. Für viele wichtige …

Modern stereoselective synthesis of chiral sulfinyl compounds

E Wojaczyńska, J Wojaczyński - Chemical reviews, 2020 - ACS Publications
Chiral sulfinyl compounds, sulfoxides, sulfoximines, sulfinamides, and other derivatives, play
an important role in asymmetric synthesis as versatile auxiliaries, ligands, and catalysts …

Rh (III)-catalyzed cascade reactions of sulfoxonium ylides with α-diazocarbonyl compounds: an access to highly functionalized naphthalenones

X Chen, M Wang, X Zhang, X Fan - Organic letters, 2019 - ACS Publications
An unprecedented cascade reaction of benzoyl sulfoxonium ylides with α-diazocarbonyl
compounds leading to the formation of highly functionalized naphthalenones containing a β …

Palladium/PC-Phos-catalyzed enantioselective arylation of general sulfenate anions: scope and synthetic applications

L Wang, M Chen, P Zhang, W Li… - Journal of the American …, 2018 - ACS Publications
Herein we reported an efficient palladium-catalyzed enantioselective arylation of both alkyl
and aryl sulfenate anions to deliver various chiral sulfoxides in good yields (up to 98%) with …

Sulfoxide and sulfone synthesis via electrochemical oxidation of sulfides

JK Park, S Lee - The Journal of Organic Chemistry, 2021 - ACS Publications
The oxidation of diaryl sulfides and aryl alkyl sulfides to the corresponding sulfoxides and
sulfones under electrochemical conditions is reported. Sulfoxides are selectively obtained in …

The use of the sterically demanding IPr* and related ligands in catalysis

F Izquierdo, S Manzini, SP Nolan - Chemical Communications, 2014 - pubs.rsc.org
This account highlights the synthesis and applications of one of the very bulky NHC ligands,
IPr*(1, 3-bis (2, 6-bis (diphenylmethyl)-4-methylphenyl) imidazo-2-ylidene). This ligand and …

A Sulfoxide Reagent for One‐Pot, Three‐Component Syntheses of Sulfoxides and Sulfinamides

F Saito - Angewandte Chemie International Edition, 2022 - Wiley Online Library
Sulfoxides and sulfinamides represent versatile sulfur functional groups found in ligands,
chiral auxiliaries, and bioactive molecules. Canonical two‐component syntheses, however …

Diaryl Sulfoxides from Aryl Benzyl Sulfoxides: A Single Palladium‐Catalyzed Triple Relay Process

T Jia, A Bellomo, S Montel, M Zhang… - Angewandte Chemie …, 2014 - Wiley Online Library
A novel approach to produce diaryl sulfoxides from aryl benzyl sulfoxides is reported.
Optimization of the reaction conditions was performed using high‐throughput …