Synthesis of 3d Metallic Single-Molecule Magnets
G Aromí, EK Brechin - Single-molecule magnets and related phenomena, 2006 - Springer
The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …
Rational Assembly of High‐Spin Polynuclear Magnetic Complexes into Coordination Networks: the Case of a [Mn4] Single‐Molecule Magnet Building Block
The synthesis of transition‐metal high‐spin complexes and of infinite coordination networks
of these high‐spin carriers now represents a recognized subdiscipline of coordination …
of these high‐spin carriers now represents a recognized subdiscipline of coordination …
Structural variation from 1D to 3D: effects of ligands and solvents on the construction of lead (II)–organic coordination polymers
J Yang, GD Li, JJ Cao, Q Yue, GH Li… - … –A European Journal, 2007 - Wiley Online Library
A series of PbII coordination polymers [Pb (ndc)(dpp)](1),[Pb (ndc)(ptcp)]⋅ 0.5 H2O (2),[Pb
(ndc)(dppz)](3),[Pb (ndc)(tcpn) 2](4),[Pb2 (ndc) 2 (tcpp)](5),[Pb (Hndc) 2]⋅ H2O (6),[Pb …
(ndc)(dppz)](3),[Pb (ndc)(tcpn) 2](4),[Pb2 (ndc) 2 (tcpp)](5),[Pb (Hndc) 2]⋅ H2O (6),[Pb …
Single-molecule magnets: a molecular approach to nanoscale magnetic materials
G Christou - Polyhedron, 2005 - Elsevier
A brief survey is provided of single-molecule magnets (SMMs), or molecular nanomagnets.
The [Mn12O12 (O2CR) 16 (H2O) 4](Mn12; R= various) family of SMMs continues to be the …
The [Mn12O12 (O2CR) 16 (H2O) 4](Mn12; R= various) family of SMMs continues to be the …
Significant increase of the barrier energy for magnetization reversal of a single-4f-ionic single-molecule magnet by a longitudinal contraction of the coordination space
S Takamatsu, T Ishikawa, S Koshihara… - Inorganic …, 2007 - ACS Publications
Two-electron oxidation of [{Pc (OEt) 8} 2TbIII]-[Pc (OEt) 8= dianion of 2, 3, 9, 10, 16, 17, 23,
24-octaethoxyphthalocyanine], which leads to a longitudinal contraction of the coordination …
24-octaethoxyphthalocyanine], which leads to a longitudinal contraction of the coordination …
Using tripodal alcohols to build high-spin molecules and single-molecule magnets
EK Brechin - Chemical communications, 2005 - pubs.rsc.org
Using tripodal alcohols to build high-spin molecules and single-molecule magnets - Chemical
Communications (RSC Publishing) DOI:10.1039/B510102F Royal Society of Chemistry View …
Communications (RSC Publishing) DOI:10.1039/B510102F Royal Society of Chemistry View …
A family of mixed-metal cyanide cubes with alternating octahedral and tetrahedral corners exhibiting a variety of magnetic behaviors including single molecule …
A series of structurally related pseudocubic metal cyanide clusters of Re (II) and 3d metal
ions [{MX} 4 {Re (triphos)(CN) 3} 4](M= Mn, Fe, Co, Ni, Zn; X= Cl, I,-OCH3) have been …
ions [{MX} 4 {Re (triphos)(CN) 3} 4](M= Mn, Fe, Co, Ni, Zn; X= Cl, I,-OCH3) have been …
DFT Computational Rationalization of an Unusual Spin Ground State in an Mn12 Single‐Molecule Magnet with a Low‐Symmetry Loop Structure
D Foguet‐Albiol, TA O'Brien… - Angewandte Chemie …, 2005 - Wiley Online Library
Single-molecule magnets (SMMs) represent a molecular approach to nanoscale magnetic
materials. They are molecules possessing a large barrier (versus kT) to magnetization …
materials. They are molecules possessing a large barrier (versus kT) to magnetization …
Inducing Single-Molecule Magnetism in a Family of Loop-of-Loops Aggregates: Heterometallic Mn40Na4 Clusters and the Homometallic Mn44 Analogue
EE Moushi, C Lampropoulos… - Journal of the …, 2010 - ACS Publications
The syntheses, crystal structures, and magnetic properties of a new family of heterometallic
Mn40Na4 and homometallic Mn44 loop-of-loops aggregates are reported. The reactions of …
Mn40Na4 and homometallic Mn44 loop-of-loops aggregates are reported. The reactions of …
Synthetic Factors Determining the Curvature and Nuclearity of the Giant Mn70 and Mn84 Clusters with a Torus Structure of ∼4 nm Diameter
AR Hale, KA Abboud, G Christou - Inorganic Chemistry, 2023 - ACS Publications
New members of the Mn70 and Mn84 torus-like cluster family have been prepared from a
hybrid comproportionation–alcoholysis reaction of [Mn12O12 (O2CR) 16 (H2O) 4] in alcohol …
hybrid comproportionation–alcoholysis reaction of [Mn12O12 (O2CR) 16 (H2O) 4] in alcohol …