Cyclic iron tetracarbenes are an emerging class of macrocyclic iron N-heterocyclic carbene
(NHC) complexes. They can be considered as an organometallic compound class inspired …

The first macrocyclic and abnormally coordinating, mesoionic N-heterocyclic carbene iron
complex has been synthesised and characterised via ESI-MS, EA, SC-XRD, CV, NMR and …

The tripodal compounds [(TMG3trphen) MII–solv](PF6) 2 (M= Mn, Fe, Co; solv= MeCN, DMF)
and bipodal analogues [(TMG2biphen) MII (NCMe) x](PF6) 2 (x= 3 for Mn, Fe; x= 2 for Co) …

Nitrene transfer reactions have emerged as one of the most powerful and versatile ways to
insert an amine function to various kinds of hydrocarbon substrates. However, the …

The bipodal compounds [(TMG2biphenN-R) CuI–NCMe](PF6)(R= Me, Ar (4-CF3Ph-)) and
[(TMG2biphenN-Me) CuI–I] have been synthesized with ligands that feature a diarylmethyl …

A comprehensive computational study on the underlying reactivity of iron tetra-NHC
complexes for C2+ N1 aziridination catalysis is presented. A library of 18 unique iron tetra …

Treatment of Mn (N (SiMe3) 2) 2 (THF) 2 with bulky chelating bis (alkoxide) ligand [1, 1′:
4′, 1′′-terphenyl]-2, 2′′-diylbis (diphenylmethanol)(H2 [O-terphenyl-O] Ph) formed a …

A chiral tetra-NHC iron (II) complex and its disparate reactivity with multiple organic azides is
reported. Both aryl and alkyl azides react with the iron (II) complex yielding three distinct …

In the frame of a coordination chemistry study on hybrid bis (N-heterocyclic carbene)-bis
(phenolate) ligands (L), the synthesis of novel Fe (III), Cr (III) and Ni (II) complexes is …

Bis (pyrazolyl) borate complexes [BBN (pzR) 2] Cu (I) were evaluated as catalysts in the
reaction of carbene/nitrene transfer and addition to C= C bonds of a wide range of aromatic …