Water gas shift reaction for hydrogen production and carbon dioxide capture: A review

WH Chen, CY Chen - Applied Energy, 2020 - Elsevier
The water gas shift reaction is an important and commonly employed reaction in the
industry. In the water gas shift reaction, hydrogen is produced from water or steam while …

Formation of intermetallic compounds by reactive metal–support interaction: a frequently encountered phenomenon in catalysis

S Penner, M Armbrüster - ChemCatChem, 2015 - Wiley Online Library
This Review discusses the structural and catalytic aspects of the recently introduced reactive
metal–support interaction. This special term was coined to account for the inability of the …

Intermetallic compounds: promising inorganic materials for well-structured and electronically modified reaction environments for efficient catalysis

S Furukawa, T Komatsu - Acs Catalysis, 2017 - ACS Publications
An overview of the catalytic properties of intermetallic compounds has been made to provide
a comprehensive understanding regarding (1) what intermetallic catalysts can do,(2) their …

[HTML][HTML] Pd/ZnO catalysts for direct CO2 hydrogenation to methanol

H Bahruji, M Bowker, G Hutchings, N Dimitratos… - Journal of catalysis, 2016 - Elsevier
The direct hydrogenation of CO 2 into methanol is crucial for providing a means of CO 2
fixation and a way to store cleanly produced hydrogen in a more energy-dense and …

Reactive metal–support interactions at moderate temperature in two-dimensional niobium-carbide-supported platinum catalysts

Z Li, Y Cui, Z Wu, C Milligan, L Zhou, G Mitchell, B Xu… - Nature Catalysis, 2018 - nature.com
The reactive metal–support interaction (RMSI) offers electronic, geometric and
compositional effects that can be used to tune catalytic active sites. Generally, supports other …

PdZn intermetallic nanostructure with Pd–Zn–Pd ensembles for highly active and chemoselective semi-hydrogenation of acetylene

H Zhou, X Yang, L Li, X Liu, Y Huang, X Pan… - Acs …, 2016 - ACS Publications
Intermetallic alloying of one active metal to another inert metal provides not only the
improved dispersion of active centers but also a unique and homogeneous ensemble of …

Size and Support Effects for the Water–Gas Shift Catalysis over Gold Nanoparticles Supported on Model Al2O3 and TiO2

M Shekhar, J Wang, WS Lee, WD Williams… - Journal of the …, 2012 - ACS Publications
The water–gas shift (WGS) reaction rate per total mole of Au under 7% CO, 8.5% CO2, 22%
H2O, and 37% H2 at 1 atm for Au/Al2O3 catalysts at 180° C and Au/TiO2 catalysts at 120° C …

Bimetallic Ni–Cu catalyst supported on CeO2 for high-temperature water–gas shift reaction: Methane suppression via enhanced CO adsorption

ET Saw, U Oemar, XR Tan, Y Du, A Borgna, K Hidajat… - Journal of catalysis, 2014 - Elsevier
The formation of methane as the undesired side product is one of the major issues in the
water–gas shift (WGS) reaction, particularly for nickel-based catalysts. A detailed study of Ni …

Improving the Hydrogenation Function of Pd/γ-Al2O3 Catalyst by Rh/γ-Al2O3 Addition in CO2 Methanation at Low Temperature

A Karelovic, P Ruiz - ACS catalysis, 2013 - ACS Publications
Catalytic CO2 methanation at mild conditions (T≤ 200° C) was studied over catalysts
prepared by mechanically mixing in different proportions Rh (2 wt%)/γ-Al2O3 and Pd (5 …

Formation and characterization of PdZn alloy: a very selective catalyst for alkyne semihydrogenation

MW Tew, H Emerich… - The Journal of Physical …, 2011 - ACS Publications
The formation of a PdZn alloy from a 4.3% Pd/ZnO catalyst was characterized by combined
in situ high-resolution X-ray diffraction (HRXRD) and X-ray absorption spectroscopy (XAS) …