Influence of Tuned Linker Functionality on Modulation of Magnetic Properties and Relaxation Dynamics in a Family of Six Isotypic Ln2 (Ln = Dy and Gd) Complexes

S Mukherjee, J Lu, G Velmurugan, S Singh… - Inorganic …, 2016 - ACS Publications
A coordination complex family comprising of six new dinuclear symmetric lanthanide
complexes, namely,[Ln2 (L x) 2 (L′) 2 (CH3OH) 2]· y G (H2L x: three related yet distinct …

Structure and Magnetism of LnIII2 (Ln= Gd, Tb, Dy, and Ho) Assemblies Constructed from a Bis (Hydrazone) Compartmental Ligand: Slow Magnetic Relaxation in the …

P Bhattacharya, R Bag, S Satpathi, SK Pati… - Crystal Growth & …, 2023 - ACS Publications
The aim of the paper was to synthesize a series of LnIII2 (Ln= Gd, Tb, Dy, and Ho)
complexes that offer a great perspective to construct functional magnetic materials. Here, we …

Lanthanide Phosphonates and Phosphates in Molecular Magnetism

J Ali, P Kumar, V Chandrasekhar - Chemistry–An Asian Journal, 2024 - Wiley Online Library
Phosphonate and phosphate ligands have historically received less attention when
compared to the widely prevalent carboxylate ligand system. Phosphonates possess …

High-Coordinate Mononuclear Ln (III) Complexes: Synthetic Strategies and Magnetic Properties

J Acharya, P Kalita, V Chandrasekhar - Magnetochemistry, 2020 - mdpi.com
Single-molecule magnets involving monometallic 4f complexes have been investigated
extensively in last two decades to understand the factors that govern the slow magnetization …

Interplay between anisotropy and magnetic exchange to modulate the magnetic relaxation behaviours of phenoxo bridged Dy 2 dimers with axial β-diketonate co …

S Roy, P Shukla, N Ahmed, MH Du, I Tarannum… - Dalton …, 2022 - pubs.rsc.org
A series of Schiff base LH ((E)-2-((pyridin-2-ylmethylene) amino) phenol) supported
phenoxo bridged symmetric [Dy2 (L) 2 (hfac) 4](1),[Dy2 (L) 2 (tfac) 4](2) and asymmetric [Dy2 …

Syntheses, Structures, and Magnetic Properties of Novel [3× 1+ 2× 1] Pentanuclear Zinc (II)-Lanthanide (III) Cocrystal Complexes: Slow Magnetic Relaxation Behavior …

S Roy, J Du, EM Manohar, T Aziz, TK Pal… - Crystal Growth & …, 2023 - ACS Publications
A new family of 3d-4f polynuclear cocrystals [LnZn2L2 (CH3CO2) 4]·[Zn2Cl4L]· H2O [where
LnIII= Gd (1), Tb (2), and Dy (3)] are synthesized by the sequential reaction of a tetradentate …

Three series of heterometallic Ni II–Ln III Schiff base complexes: synthesis, crystal structures and magnetic characterization

L Jiang, Y Liu, X Liu, J Tian, S Yan - Dalton Transactions, 2017 - pubs.rsc.org
Three series of NiII–LnIII complexes were synthesized with the general formulae [(μ3-CO3) 2
{Ni (HL)(CH3–CH2OH) Ln (CH3COO)} 2]· 2CH3CH2OH (1–6)(Ln= Tb (1), Dy (2), Ho (3), Er …

CO2 Fixation by Dimeric Tb(III) Complexes: Synthesis, Structure, and Magnetism

M Dolai, S Biswas, E Moreno-Pineda… - Crystal Growth & …, 2023 - ACS Publications
Two dinuclear complexes,[Tb2 (L1) 2 (piv) 2 (NO3) 2]· H2O (1) and [Tb2 (L2) 2 (CF3CO2) 2
(H2O) 4]. 2NO3 (2), have been prepared and characterized by single-crystal X-ray …

Exchange-Bias Quantum Tunneling of the Magnetization in a Dysprosium Dimer

M Dolai, E Moreno-Pineda, W Wernsdorfer… - The Journal of …, 2021 - ACS Publications
Single-molecule magnets (SMMs) have been shown to possess bewildering phenomena
leading to their proposal in several futuristic applications ranging from data storage devices …

Exploring Tuning of Structural and Magnetic Properties by Modification of Ancillary β-Diketonate Co-ligands in a Family of Near-Linear Tetranuclear DyIII Complexes

J Acharya, S Biswas, J van Leusen… - Crystal Growth & …, 2018 - ACS Publications
Three tetranuclear DyIII complexes,[Dy4 (LH) 2 (CH3OH) 4 (acac) 6](1),[Dy4 (LH) 2
(CH3OH) 4 (hmacac) 6]· 2CH3OH (2), and [Dy4 (LH) 2 (CH3OH) 4 (dpacac) 6]· 2CHCl3 …