Second-order nonlinear optical materials: recent advances in chromophore design

T Verbiest, S Houbrechts, M Kauranen… - Journal of Materials …, 1997 - pubs.rsc.org
This paper deals with recent and important developments in the field of organic materials for
second-order nonlinear optics. Attention is drawn to current trends in chromophore design …

Second-order nonlinear optics in coordination chemistry: An open door towards multi-functional materials and molecular switches

PG Lacroix, I Malfant, C Lepetit - Coordination Chemistry Reviews, 2016 - Elsevier
Various inorganic and organometallic complexes exhibiting quadratic nonlinear optical
(NLO) properties (ie, linearly correlated to the square of the electric field E 2) are reviewed …

Electric field modulated nonlinear optical properties of donor-acceptor polyenes: sum-over-states investigation of the relationship between molecular polarizabilities …

F Meyers, SR Marder, BM Pierce… - Journal of the American …, 1994 - ACS Publications
We investigate the influence of an external, static electric field upon the relationship between
the structure, spatial distribution of electron density, and linear and nonlinear polarizabilities …

Push− Pull arylethynyl porphyrins: new chromophores that exhibit large molecular first-order hyperpolarizabilities

SM LeCours, HW Guan, SG DiMagno… - Journal of the …, 1996 - ACS Publications
A new class of chromophores has been fabricated that features both electron-releasing and
electron-withdrawing groups fused via an intervening ethynyl moiety to the carbon …

Molecular materials possessing switchable quadratic nonlinear optical properties

BJ Coe - Chemistry–A European Journal, 1999 - Wiley Online Library
Reversible switching of quadratic NLO responses can be achieved in organic and metallo‐
organic molecular compounds by application of various external stimuli. Strategies for the …

[图书][B] Second-order nonlinear optical characterization techniques: an introduction

T Verbiest, K Clays, V Rodriguez - 2009 - taylorfrancis.com
Although chemists, biochemists, biologists, and material scientists are often interested in
using nonlinear optical techniques for characterizing their samples, they seldom have the …

Acetylenyl-linked, porphyrin-bridged, donor− acceptor molecules: a theoretical analysis of the molecular first hyperpolarizability in highly conjugated push− pull …

S Priyadarshy, MJ Therien… - Journal of the American …, 1996 - ACS Publications
We describe the theoretical basis for the exceptionally large molecular first
hyperpolarizabilities inherent to (5, 15-diethynylporphinato) metal-bridged donor− acceptor …

Carbon dioxide and oxygen isotope anomalies in the mesosphere and stratosphere

MH Thiemens, T Jackson, EC Zipf, PW Erdman… - Science, 1995 - science.org
Isotopic (δ17O and δ18O) measurements of stratospheric and mesospheric carbon dioxide
(CO2) and oxygen (O2), along with trace species concentrations (N2O, CO, and CO2), were …

Two‐way molecular switches with large nonlinear optical contrast

F Mançois, JL Pozzo, J Pan, F Adamietz… - … A European Journal, 2009 - Wiley Online Library
Molecular switches: Highly efficient acido‐and photoswitchable frequency doublers (see
scheme) based on the indolinooxazolidine core are studied by means of hyper‐Rayleigh …

Supramolecular second-order nonlinearity of polymers with orientationally correlated chromophores

M Kauranen, T Verbiest, C Boutton, MN Teerenstra… - Science, 1995 - science.org
Nonlinear optical chromophores can be organized as orientationally correlated side groups
of polymers with a rigid backbone. In such an organization, each chromophore contributes …