[HTML][HTML] Affinity of deep eutectic solvents with aromatic molecules and aromatic nanostructures in chemical transformations

SV Giofrè, C Celesti, G Mistretta, M Tiecco - Current Opinion in Green and …, 2023 - Elsevier
Abstract Deep Eutectic Solvents (DESs) are an innovative class of green liquids that are
finding fruitful applications as substitutes of polluting organic solvents. One of the topics in …

Nuclear Magnetic Resonance Relaxation Pathways in Electrolytes for Energy Storage

CC Fraenza, SG Greenbaum, SN Suarez - International Journal of …, 2023 - mdpi.com
Nuclear Magnetic Resonance (NMR) spin relaxation times have been an instrumental tool in
deciphering the local environment of ionic species, the various interactions they engender …

Anion dynamics and motional decoupling in a glycerol–choline chloride deep eutectic solvent studied by one-and two-dimensional 35 Cl NMR

Y Hinz, J Beerwerth, R Böhmer - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Chlorine-35 is among the few nuclides that provide an experimental handle on the anion
dynamics in choline based deep eutectic solvents. By combining several nuclear magnetic …

Molecular Modes Elucidate the Nuclear Magnetic Resonance Relaxation of Viscous Fluids

A Valiya Parambathu… - The Journal of …, 2024 - ACS Publications
The Bloembergen, Purcell, and Pound (BPP) theory of nuclear magnetic resonance (NMR)
relaxation in fluids dating back to 1948 continues to be the linchpin in interpreting NMR …

[HTML][HTML] Insights into the structural features of deep eutectic solvents: the eutectic point as an unicum in their physical properties and the surface tension as a method …

M Fronduti, T Del Giacco, E Rossi, M Tiecco… - Journal of Molecular …, 2023 - Elsevier
Abstract Deep Eutectic Solvents (DESs) are a class of solvents that are increasing their
relevance thanks to their environmental-friendly characteristics, to their catalytic properties …

Perspective—Hydrogen Bonded Concentrated Electrolytes for Redox Flow Batteries: Limitations and Prospects

R Ghahremani, RF Savinell… - Journal of the …, 2022 - iopscience.iop.org
This perspective provides a brief overview of the recent work on electrolytes with hydrogen
(H)-bonding network, specifically the deep eutectic solvents (DESs), and outlines important …

Translational and reorientational dynamics in carboxylic acid-based deep eutectic solvents

A Schulz, K Moch, Y Hinz, P Lunkenheimer… - The Journal of …, 2024 - pubs.aip.org
The glass formation and the dipolar reorientational motions in deep eutectic solvents (DESs)
are frequently overlooked, despite their crucial role in defining the room-temperature …

2H and 13C nuclear spin relaxation unravels dynamic heterogeneities in deep eutectic solvents of ethylene glycol, glycerol, or urea with choline chloride

Y Hinz, R Böhmer - The Journal of Chemical Physics, 2023 - pubs.aip.org
Using deuteron spin-lattice and spin-spin relaxometry, the reorientational dynamics of
ethaline (choline chloride/ethylene glycol) and reline (choline chloride/urea) are studied in a …

Interfacial Nanostructure and Hydrogen Bond Networks of Choline Chloride and Glycerol Mixtures Probed with X-ray and Vibrational Spectroscopies

P Kim, C Weeraratna, S Nemšák, N Dias… - The Journal of …, 2024 - ACS Publications
The molecular distribution at the liquid–vapor interface and evolution of the hydrogen bond
interactions in mixtures of glycerol and choline chloride are investigated using X-ray …

Deuteron magnetic resonance study of glyceline deep eutectic solvents: Selective detection of choline and glycerol dynamics

Y Hinz, R Böhmer - The Journal of Chemical Physics, 2022 - pubs.aip.org
Glyceline, a green solvent considered for various electrochemical applications, represents a
multi-component glass former. Viewed from this perspective, the choline cation and the …