Tri-and tetrasubstituted olefins are widely present in biologically active molecules and
functional materials. However, the methods for the stereoselective construction of such …

The use of ynamides in organic synthesis has gained significant attention due to their ability
to provide access to complex molecular structures through transformations such as 1, 2 …

An electrochemically driven nickel-catalyzed enantioselective reductive cross-coupling of
aryl aziridines with alkenyl bromides has been developed, affording enantioenriched β-aryl …

Catalytic functionalization of alkynes with organoboron reagents provides a straightforward
access to stereochemically defined multisubstituted alkenes, which are structural motifs …

Herein, we report a Ni-catalyzed C (sp2)–H hydroxylation of aryl bromides with N2O as an
oxygen-atom donor. The reaction is enabled by a 1, 4-Ni translocation that results in …

Precise stereocontrol of functionalized alkenes represents a long-standing research topic in
organic synthesis. Nevertheless, the development of a catalytic, easily tunable synthetic …

The introduction of fluorine‐containing groups into organic molecules can significantly affect
their physical and chemical properties and has long been used as an effective strategy for …

The implementation of HCN-free transfer hydrocyanation reactions on laboratory scales has
recently been achieved by using HCN donor reagents under nickel-and Lewis acid co …

Herein, we report a nickel-catalyzed asymmetric three-component trans-
dicarbofunctionalization of β-substituted α-naphthyl propargylic alcohols using readily …

The catalytic hydroarylation of alkynes has emerged as an excellent methodology for the
synthesis of functionalized alkenes with excellent levels of regio-and stereocontrol (syn) …