Metal–organic framework-based hierarchically porous materials: synthesis and applications

G Cai, P Yan, L Zhang, HC Zhou, HL Jiang - Chemical Reviews, 2021 - ACS Publications
Metal–organic frameworks (MOFs) have been widely recognized as one of the most
fascinating classes of materials from science and engineering perspectives, benefiting from …

Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

J Liu, TA Goetjen, Q Wang, JG Knapp… - Chemical Society …, 2022 - pubs.rsc.org
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

Metal–organic framework-based catalysts with single metal sites

YS Wei, M Zhang, R Zou, Q Xu - Chemical Reviews, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Coordination environment dependent selectivity of single-site-Cu enriched crystalline porous catalysts in CO2 reduction to CH4

Y Zhang, LZ Dong, S Li, X Huang, JN Chang… - Nature …, 2021 - nature.com
The electrochemical CO2 reduction to high-value-added chemicals is one of the most
promising and challenging research in the energy conversion field. An efficient ECR catalyst …

Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

The effect of coordination environment on the activity and selectivity of single-atom catalysts

Y Zhang, J Yang, R Ge, J Zhang, JM Cairney… - Coordination Chemistry …, 2022 - Elsevier
Traditional heterogeneous catalysts with noble metals as active sites only have surface-
active substances involved in the catalytic reactions, which greatly reduces the material …

Generating catalytic sites in UiO-66 through defect engineering

X Feng, HS Jena, C Krishnaraj, K Leus… - … Applied Materials & …, 2021 - ACS Publications
UiO-66 is regarded as an epitome of metal–organic frameworks (MOFs) because of its
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …

Catalysis by metal organic frameworks: perspective and suggestions for future research

D Yang, BC Gates - Acs Catalysis, 2019 - ACS Publications
Metal organic frameworks (MOFs) have drawn wide attention as potential catalysts, offering
high densities of catalytic sites in high-area porous solids, some with stabilities at high …

Metal–organic frameworks: Structures and functional applications

L Jiao, JYR Seow, WS Skinner, ZU Wang, HL Jiang - Materials Today, 2019 - Elsevier
Abstract Metal–organic frameworks (MOFs), constructed by organic linkers and metal nodes,
are a new class of crystalline porous materials with significant application potentials …