Redox and addition chemistry of quinoid compounds and its biological implications

A Brunmark, E Cadenas - Free Radical Biology and Medicine, 1989 - Elsevier
The overall biological activity of quinones is a function of the physico-chemical properties of
these compounds, which manifest themselves in a critical bimolecular reaction with …

Oxidation of phenols by triplet aromatic ketones in aqueous solution

S Canonica, B Hellrung, J Wirz - The Journal of Physical …, 2000 - ACS Publications
Aromatic ketones efficiently mediate the photo-oxidative degradation of phenols in aerated
aqueous solution, a process likely to be relevant in sunlit natural waters. Absolute …

Photo-and radiation-induced one-electron oxidation of methionine in various structural environments studied by time-resolved techniques

B Marciniak, K Bobrowski - Molecules, 2022 - mdpi.com
Oxidation of methionine (Met) is an important reaction that plays a key role in protein
modifications during oxidative stress and aging. The first steps of Met oxidation involve the …

Quenching of excited triplet states by dissolved natural organic matter

J Wenk, SN Eustis, K McNeill… - Environmental science & …, 2013 - ACS Publications
Excited triplet states of aromatic ketones and quinones are used as proxies to assess the
reactivity of excited triplet states of the dissolved organic matter (3DOM*) in natural waters …

Sorbic acid as a quantitative probe for the formation, scavenging and steady-state concentrations of the triplet-excited state of organic compounds

JE Grebel, JJ Pignatello, WA Mitch - Water research, 2011 - Elsevier
Sorbic acid (trans, trans-hexadienoic acid) was developed as a probe for the quantification
of the formation rate, overall solution scavenging rate and steady-state concentrations of …

Investigating the mechanism of phenol photooxidation by humic substances

KS Golanoski, S Fang, R Del Vecchio… - … science & technology, 2012 - ACS Publications
To probe the mechanism of the photosensitized loss of phenols by humic substances (HS),
the dependence of the initial rate of 2, 4, 6-trimethylphenol (TMP) loss (RTMP) on dioxygen …

Oxidation of aquatic organic contaminants induced by excited triplet states

S Canonica - Chimia, 2007 - chimia.ch
The developments of the last fifteen years in the field of triplet-induced degradation of
aquatic organic contaminants are reviewed. There is increasing evidence that the elusive …

Aqueous oxidation of phenylurea herbicides by triplet aromatic ketones

S Canonica, B Hellrung, P Müller… - Environmental science & …, 2006 - ACS Publications
Excited triplet states of dissolved natural organic matter (DOM) are important players for the
transformation of organic chemical contaminants in sunlit natural waters. The present study …

Photoinduced oxidation of sea salt halides by aromatic ketones: a source of halogenated radicals

A Jammoul, S Dumas, B D'anna… - … Chemistry and Physics, 2009 - acp.copernicus.org
The interactions between triplet state benzophenone and halide anion species (Cl<
sup&minu;, Br< sup&minu; and I< sup&minu; have been studied by laser flash photolysis (at …

Mechanisms of oxygen activation and reactive oxygen species detoxification

E Cadenas - Oxidative stress and antioxidant defenses in biology, 1995 - Springer
The biochemistry of 'reactive oxygen species'(ROS) is an important field with practical
implications, because whereas oxygen is an essential component for living organisms, the …