3 Advances in the coordination chemistry of amidinate and guanidinate ligands

FT Edelmann - Advances in organometallic chemistry, 2008 - books.google.com
The quest for alternatives to cyclopentadienyl-based ligands has led to a recent renaissance
of N-centered donor ligands in various fields of organometallic and coordination chemistry …

Atomic layer deposition of metals: Precursors and film growth

DJ Hagen, ME Pemble, M Karppinen - Applied Physics Reviews, 2019 - pubs.aip.org
The coating of complex three-dimensional structures with ultrathin metal films is of great
interest for current technical applications, particularly in microelectronics, as well as for basic …

Precursors and chemistry for the atomic layer deposition of metallic first row transition metal films

TJ Knisley, LC Kalutarage, CH Winter - Coordination Chemistry Reviews, 2013 - Elsevier
Recent trends in the microelectronics industry are requiring the growth of metallic first row
transition metal films by the atomic layer deposition (ALD) method. The ALD growth of noble …

Precursor design and reaction mechanisms for the atomic layer deposition of metal films

KB Ramos, MJ Saly, YJ Chabal - Coordination chemistry reviews, 2013 - Elsevier
Deposition of thin films with desired compositions, conformality and bonding to substrates is
a key component in nanotechnology research. The growth of metal films by atomic layer …

Direct-liquid-injection chemical vapor deposition of nickel nitride films and their reduction to nickel films

Z Li, RG Gordon, V Pallem, H Li… - Chemistry of …, 2010 - ACS Publications
Smooth and continuous films of nickel nitride (NiN x) with excellent step coverage were
deposited from a novel nickel amidinate precursor, Ni (MeC (N t Bu) 2) 2, and either …

Origin of Decomposition in a Family of Molybdenum Precursor Compounds

MA Land, G Bacic, KN Robertson, ST Barry - Inorganic Chemistry, 2022 - ACS Publications
The bis (tert-butylimido)-molybdenum (VI) framework has been used successfully in the
design of vapor-phase precursors for molybdenum-containing thin films, so understanding …

Theoretical design and computational screening of precursors for atomic layer deposition

G Fang, L Xu, Y Cao, A Li - Coordination Chemistry Reviews, 2016 - Elsevier
An effective precursor is a prerequisite and key to the success of atomic layer deposition
(ALD). Currently, the design of more effective precursors is an important aspect of the …

Low temperature, selective atomic layer deposition of nickel metal thin films

MM Kerrigan, JP Klesko, KJ Blakeney… - ACS applied materials …, 2018 - ACS Publications
We report the growth of nickel metal films by atomic layer deposition (ALD) employing bis (1,
4-di-tert-butyl-1, 3-diazadienyl) nickel and tert-butylamine as the precursors. A range of …

Cut-and-pasting ligands: The structure/function relationships of a thermally robust Mo (VI) precursor

MA Land, DA Dimova, KN Robertson… - Journal of Vacuum …, 2023 - pubs.aip.org
The bis (tert-butylimido)-molybdenum (VI) framework has previously been used for the
successful atomic layer deposition (ALD) and chemical vapor deposition of many …

Bis(tert‐butylimido)‐bis(dialkylamido) Complexes of Molybdenum as Atomic Layer Deposition (ALD) Precursors for Molybdenum Nitride: the Effect of the Alkyl Group

V Miikkulainen, M Suvanto… - Chemical Vapor …, 2008 - Wiley Online Library
Abstract Bis (tert‐butylimido)‐bis (diethylamido) molybdenum [(tBuN) 2Mo (NEt2) 2] and bis
(tert‐butylimido)‐bis (di‐isopropylamido) molybdenum [(tBuN) 2Mo (NiPr2) 2], possible …