Theoretical advances in polariton chemistry and molecular cavity quantum electrodynamics

A Mandal, MAD Taylor, BM Weight… - Chemical …, 2023 - ACS Publications
When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called
polaritons, are formed due to quantum light–matter interactions. With the experimental …

Manipulating matter by strong coupling to vacuum fields

FJ Garcia-Vidal, C Ciuti, TW Ebbesen - Science, 2021 - science.org
BACKGROUND One of the most important phenomena in cavity quantum electrodynamics
(cQED) is the so-called strong coupling regime, which appears when the interaction …

Chemistry under vibrational strong coupling

K Nagarajan, A Thomas… - Journal of the American …, 2021 - ACS Publications
Over the past decade, the possibility of manipulating chemistry and material properties using
hybrid light–matter states has stimulated considerable interest. Hybrid light–matter states …

Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

Swinging between shine and shadow: Theoretical advances on thermally activated vibropolaritonic chemistry

JA Campos-Gonzalez-Angulo, YR Poh, M Du… - The Journal of …, 2023 - pubs.aip.org
Polariton chemistry has emerged as an appealing branch of synthetic chemistry that
promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are …

Quantum effects in chemical reactions under polaritonic vibrational strong coupling

PY Yang, J Cao - The Journal of Physical Chemistry Letters, 2021 - ACS Publications
The electromagnetic field in an optical cavity can dramatically modify and even control
chemical reactivity via vibrational strong coupling (VSC). Since the typical vibration and …

Catalysis by dark states in vibropolaritonic chemistry

M Du, J Yuen-Zhou - Physical Review Letters, 2022 - APS
Collective strong coupling between a disordered ensemble of N localized molecular
vibrations and a resonant optical cavity mode gives rise to two polariton and N-1≫ 2 dark …

Modifying Woodward–Hoffmann stereoselectivity under vibrational strong coupling

A Sau, K Nagarajan, B Patrahau… - Angewandte Chemie …, 2021 - Wiley Online Library
Vibrational strong coupling (VSC) has recently been shown to change the rate and
chemoselectivity of ground‐state chemical reactions via the formation of light–matter hybrid …

Supramolecular assembly of conjugated polymers under vibrational strong coupling

K Joseph, S Kushida, E Smarsly… - Angewandte Chemie …, 2021 - Wiley Online Library
Strong coupling plays a significant role in influencing chemical reactions and tuning material
properties by modifying the energy landscapes of the systems. Here we study the effect of …

Vibropolaritonic Reaction Rates in the Collective Strong Coupling Regime: Pollak–Grabert–Hänggi Theory

M Du, YR Poh, J Yuen-Zhou - The Journal of Physical Chemistry …, 2023 - ACS Publications
Following experimental evidence that vibrational polaritons, formed from collective
vibrational strong coupling (VSC) in optical microcavities, can modify ground-state reaction …