Metal complexes of singly, doubly and triply linked porphyrins and corroles: An insight into the physicochemical properties
Metal complexes of multi‐porphyrins and multi‐corroles are unique systems that display a
host of extremely interesting properties. Availability of free meso and β positions allow …
host of extremely interesting properties. Availability of free meso and β positions allow …
Copper Coordination‐Based Nanomedicine for Tumor Theranostics
Y Han, N Xie, W Zhou - Advanced Therapeutics, 2024 - Wiley Online Library
Copper (Cu) is an essential micronutrient for a variety of basic biological processes,
including cell metabolism, proliferation, and angiogenesis. Recently, the concept of …
including cell metabolism, proliferation, and angiogenesis. Recently, the concept of …
A Bio‐inspired Cu4O4 Cubane: Effective Molecular Catalysts for Electrocatalytic Water Oxidation in Aqueous Solution
Inspired by the cubic Mn4CaO5 cluster of natural oxygen‐evolving complex in Photosystem
II, tetrametallic molecular water oxidation catalysts, especially M4O4 cubane‐like clusters …
II, tetrametallic molecular water oxidation catalysts, especially M4O4 cubane‐like clusters …
Electronic structure of copper corroles
The ground state electronic structure of copper corroles has been a topic of debate and
revision since the advent of corrole chemistry. Computational studies formulate neutral Cu …
revision since the advent of corrole chemistry. Computational studies formulate neutral Cu …
C− N bond formation from a masked high‐valent copper complex stabilized by redox non‐innocent ligands
The reactivity of a stable copper (II) complex bearing fully oxidized iminobenzoquinone
redox ligands towards nucleophiles is described. In sharp contrast with its genuine low …
redox ligands towards nucleophiles is described. In sharp contrast with its genuine low …
An Adaptable N‐Heterocyclic Carbene Macrocycle Hosting Copper in Three Oxidation States
Y Liu, SG Resch, I Klawitter, GE Cutsail III… - Angewandte …, 2020 - Wiley Online Library
A neutral hybrid macrocycle with two trans‐positioned N‐heterocyclic carbenes (NHCs) and
two pyridine donors hosts copper in three oxidation states (+ I–+ III) in a series of structurally …
two pyridine donors hosts copper in three oxidation states (+ I–+ III) in a series of structurally …
Template Synthesis of Alkyl‐Substituted Metal Isocorroles
M Hoffmann, B Cordes, C Kleeberg… - European Journal of …, 2016 - Wiley Online Library
Five metal complexes of 10, 10‐dimethylisocorrole ligands with full β‐pyrrolic substitution is
have been synthesized. The preparation of nickel (II), palladium (II), and copper (II) …
have been synthesized. The preparation of nickel (II), palladium (II), and copper (II) …
Bis‐copper (II) Complex of Triply‐linked Corrole Dimer and Its Dication
S Ooi, T Tanaka, T Ikeue, K Yamasumi… - Chemistry–An Asian …, 2019 - Wiley Online Library
Copper complexes of corroles have recently been a subject of keen interest due to their
ligand non‐innocent character and unique redox properties. Here we investigated bis …
ligand non‐innocent character and unique redox properties. Here we investigated bis …
Ruthenium–Ruthenium‐Bonded [Bis{corrolato‐ruthenium(III)}]n (n=0, +1, −1) Complexes: Model Compounds for the Photosynthetic Special Pair
W Sinha, MG Sommer, L Hettmanczyk… - … A European Journal, 2017 - Wiley Online Library
We present herein the synthesis of three new bis (corrolato‐ruthenium (III)) complexes
containing unsupported Ru–Ru bonds and their characterization in different redox states …
containing unsupported Ru–Ru bonds and their characterization in different redox states …
Accurate ionization energies for mononuclear copper complexes remain a challenge for density functional theory
Copper is ubiquitous and its one‐electron redox chemistry is central to many catalytic
processes. Modeling such chemistry requires electronic structure methods capable of the …
processes. Modeling such chemistry requires electronic structure methods capable of the …