Herein, we present a manganese‐catalyzed, branched‐selective hydroalkenylation of
terminal alkynes, under mild conditions through facile installation of a versatile silanol as a …

Hydrogen (H2) has drawn extensive attention due to its superior gravimetric capacity density
and eco-friendly nature. Nowadays, hydrogen is mainly produced by the steam reforming of …

Nickel-catalyzed anti-selective alkyne functionalization reactions are reviewed with an
emphasis on the mechanisms that lead to their observed stereoselectivity. Since the …

Water has been widely explored as a solvent and/or proton source for the development of
green chemical technologies. However, water has the capacity to take on more interesting …

Summary The Suzuki-Miyaura coupling is a fundamentally important transformation in
modern organic synthesis. The development of new reaction modes for new chemical …

This Letter outlines palladium-catalyzed regioselective (Markovnikov's) addition of aryl
boronic acids to propargyl 1, 3-dicarbonyl alkyne to accomplish olefinic/diene 1, 3 …

The regio-and stereoselective hydroarylation of internal alkynes via transition-metal
catalysis offers a direct approach for designing highly stereodefined multifunctionalized …

A gold-catalyzed intermolecular hydroarylation involving arylboronic acid has been
disclosed. This carboxylic acid-directed arylation is highly regioselective and occurs at the …

An operationally simple nickel-catalyzed hydroarylation reaction for alkynes is described.
This three-component coupling reaction utilizes commercially available alkynes and aryl …

α-Fluoro-α′-aryl ketones are crucial in pharmaceuticals and agrochemicals. However,
synthesizing unsymmetrical α-fluoro-α′-aryl ketones poses regioselective challenges. This …