Microdroplets show unique chemistry, especially in their intrinsic redox properties, and to
this we here add a case of simultaneous and spontaneous oxidation and reduction. We …

Despite the high stability of bulk water, water microdroplets possess strikingly different
properties, such as the presence of hydroxyl radicals (OH⋅) at the air–water interface …

The kinetics of organic reactions of different types in microvolumes (droplets, thin films, and
sealed tubes) show effects of gas/solution interfacial area, reaction molecularity and solvent …

The sulfur fluoride exchange (SuFEx) reaction is significant in drug discovery, materials
science, and chemical biology. Conventionally, it involves installation of SO2F followed by …

Microdroplet chemistry is attracting increasing attention for accelerated reactions at the
solution–air interface. We report herein a voltage‐controlled interfacial microreactor that …

Many important chemical transformations occur in two‐phase reactions, which are widely
used in chemical, pharmaceutical, and polymer manufacturing. We present an efficient …

Sharpless and co‐workers previously studied the [2σ+ 2σ+ 2π] cycloaddition of diethyl
azodicarboxylate (DEAD) and quadricyclane and reported that the addition of water to the …

Many reactions show much faster kinetics in microdroplets than in the bulk phase. Most
reported reactions in microdroplets mirror the products found in bulk reactions. However, the …

Thin film formats are used to study the Claisen–Schmidt base‐catalyzed condensation of 6‐
hydroxy‐1‐indanone with substituted benzaldehydes and to compare the reaction …

Forced degradation is a method of studying the stability of pharmaceuticals in order to
design stable formulations and predict drug product shelf life. Traditional methods of …