The golden age of thermally activated delayed fluorescence materials: design and exploitation

JM Dos Santos, D Hall, B Basumatary… - Chemical …, 2024 - ACS Publications
Since the seminal report by Adachi and co-workers in 2012, there has been a veritable
explosion of interest in the design of thermally activated delayed fluorescence (TADF) …

TADF Material Design: Photophysical Background and Case Studies Focusing on Cu(I) and Ag(I) Complexesa

H Yersin, R Czerwieniec, MZ Shafikov… - … : Materials Based on …, 2018 - Wiley Online Library
Designing of thermally activated delayed fluorescence (TADF) compounds with short TADF
decay time and high emission quantum yield is a challenge. This chapter introduces …

Two-coordinate thermally activated delayed fluorescence coinage metal complexes: Molecular design, photophysical characters, and device application

TY Li, SJ Zheng, PI Djurovich, ME Thompson - Chemical Reviews, 2024 - ACS Publications
Since the emergence of the first green light emission from a fluorescent thin-film organic light
emitting diode (OLED) in the mid-1980s, a global consumer market for OLED displays has …

Recent developments of photoactive Cu (I) and Ag (I) complexes with diphosphine and related ligands

H Takeda, A Kobayashi, K Tsuge - Coordination Chemistry Reviews, 2022 - Elsevier
In the past two decades, emissive Cu (I) complexes have been synthesized with various
ligands, revealing their interesting and useful photophysical properties such as high …

Ln3+ Induced Thermally Activated Delayed Fluorescence of Chiral Heterometallic Clusters Ln2Ag28

XT Wang, SR He, FW Lv, XT Wang… - Angewandte Chemie …, 2024 - Wiley Online Library
A series of TADF‐active compounds: 0D chiral Ln− Ag (I) clusters L‐/D‐Ln2Ag28‐0D (Ln=
Eu/Gd) and 2D chiral Ln− Ag (I) cluster‐based frameworks L‐/D‐Ln2Ag28‐2D (Ln= Gd) has …

Cu (I) and Ag (I) complexes with a new type of rigid tridentate N, P, P-ligand for thermally activated delayed fluorescence and OLEDs with high external quantum …

M Klein, N Rau, M Wende, J Sundermeyer… - Chemistry of …, 2020 - ACS Publications
Neutral Cu (I) and Ag (I) complexes with a new rigid tridentate N, P, P ligand (dmpzpp, 3, 5-
dimethyl-1-(2-((2-(di-o-tolyl) phosphanyl)(o-tolyl)-phosphanyl) phenyl)-1 H-pyrazole), giving …

Intersystem crossing, phosphorescence, and spin-orbit coupling. Two contrasting Cu (I)-TADF dimers investigated by milli-to micro-second phosphorescence, femto …

H Yersin, R Czerwieniec, U Monkowius… - Coordination Chemistry …, 2023 - Elsevier
Applying femto-second time-resolved spectroscopy, we study intersystem crossing times τ
(ISC) of two Cu (I) dimers, Cu 2 Cl 2 (dppb) 2 1 (dppb= 1, 2-bis-diphenylphosphino) …

Thermally activated delayed fluorescence materials for organic light-emitting diodes

X Li, S Fu, Y Xie, Z Li - Reports on Progress in Physics, 2023 - iopscience.iop.org
Recently, the remarkable advances in thermally activated delayed fluorescence (TADF)
materials have attracted much attention due to their 100% exciton utilization efficiency in …

Conformational engineering of two-coordinate gold (I) complexes: Regulation of excited-state dynamics for efficient delayed fluorescence

JG Yang, XF Song, G Cheng, S Wu… - … Applied Materials & …, 2022 - ACS Publications
Carbene–Au–amide (CMA) type complexes, in which the amide and carbene ligands act as
an electron donor (D) and acceptor (A), respectively, can exhibit strong delayed …

Palladium-catalyzed selective five-fold cascade arylation of the 12-vertex monocarborane anion by B–H activation

F Lin, JL Yu, Y Shen, SQ Zhang… - Journal of the …, 2018 - ACS Publications
A series of cage penta-arylated carboranes have been synthesized by palladium-catalyzed
intermolecular coupling of the C-carboxylic acid of the monocarba-closo-dodecaborate …