Assembling metal–organic cages as porous materials

E Sánchez-González, MY Tsang, J Troyano… - Chemical Society …, 2022 - pubs.rsc.org
There is growing interest in metal–organic cages (MOCs) as porous materials owing to their
processability in solution. The discrete molecular character and surface features of MOCs …

Post-synthetic modifications of metal–organic cages

J Liu, Z Wang, P Cheng, MJ Zaworotko… - Nature Reviews …, 2022 - nature.com
Metal–organic cages (MOCs) are discrete, supramolecular entities that consist of metal
nodes and organic linkers, which can offer solution processability and high porosity …

Hierarchical porous metal–organic gels and derived materials: from fundamentals to potential applications

JK Wychowaniec, H Saini, B Scheibe… - Chemical Society …, 2022 - pubs.rsc.org
Metal–organic gels (MOGs) emerged as a novel class of functional soft materials in which
the scaffolding framework is fabricated by metal–ligand coordination in combination with …

Rhodium-Based Metal–Organic Polyhedra Assemblies for Selective CO2 Photoreduction

AC Ghosh, A Legrand, R Rajapaksha… - Journal of the …, 2022 - ACS Publications
Heterogenization of molecular catalysts via their immobilization within extended structures
often results in a lowering of their catalytic properties due to a change in their coordination …

Pore-Networked Gels: Permanently Porous Ionic Liquid Gels with Linked Metal–Organic Polyhedra Networks

Z Wang, A Ozcan, GA Craig, F Haase… - Journal of the …, 2023 - ACS Publications
Porous liquids (PLs) are attractive materials because of their capability to combine the
intrinsic porosity of microporous solids and the processability of liquids. Most of the studies …

Pore-networked membrane using linked metal-organic polyhedra for trace-level pollutant removal and detection in environmental water

Z Wang, I Pacheco-Fernández, JE Carpenter… - Communications …, 2024 - nature.com
The wide presence of pharmaceuticals and personal care products (PPCPs) in water is a
major pollution concern even at the part per billion level, which urges their detection and …

Post‐Assembly Modification of Homochiral Titanium–Organic Cages for Recognition and Separation of Molecular Isomers

GH Chen, YP He, Y Yu, H Lv, S Li… - Angewandte Chemie …, 2023 - Wiley Online Library
A chiral metal–organic cage (MOC) was extended and fixed into a porous framework using a
post‐assembly modification strategy, which made it easier to study the host–guest chemistry …

Reversible Discrete-to-Extended Metal–Organic Polyhedra Transformation by Sulfonic Acid Surface Functionalization

J Troyano, S Horike, S Furukawa - Journal of the American …, 2022 - ACS Publications
Metal–organic polyhedra (MOPs) are molecular porous units in which desired functionalities
can be installed with precise geometrical and compositional control. By combing two …

Metal–organic polyhedra as building blocks for porous extended networks

A Khobotov‐Bakishev, L Hernández‐López… - Advanced …, 2022 - Wiley Online Library
Metal–organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and
host species in solution and are permanently porous in solid‐state. These characteristics …

Pore-Networked Soft Materials Based on Metal–Organic Polyhedra

Z Wang, S Furukawa - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus The last two decades have witnessed a tremendous development of crystalline
microporous adsorbents in a wide range of applications including molecular adsorption …