Electroreduction of CO2: Advances in the Continuous Production of Formic Acid and Formate

K Fernández-Caso, G Díaz-Sainz… - ACS Energy …, 2023 - ACS Publications
The study of the electrochemical CO2 reduction to obtain formate (HCOO–) or formic acid
(HCOOH) is receiving much attention as a promising technology. Since continuous–mode …

Design of electrocatalysts and electrodes for CO2 electroreduction to formic acid and formate

DS Tran, NN Vu, HE Nemamcha, C Boisvert… - Coordination Chemistry …, 2025 - Elsevier
Electrochemical carbon dioxide (CO 2) reduction reaction (CO 2 RR) is gaining attraction as
it enables the generation of highly valuable chemicals while mitigating greenhouse gas …

Direct Electroreduction of Carbonate to Formate

H Ma, E Ibáñez-Alé, R Ganganahalli… - Journal of the …, 2023 - ACS Publications
A cause of losses in energy and carbon conversion efficiencies during the electrochemical
CO2 reduction reaction (eCO2RR) can be attributed to the formation of carbonates (CO32–) …

Anion Exchange Facilitates the In Situ Construction of Bi/BiO Interfaces for Enhanced Electrochemical CO2‐to‐Formate Conversion Over a Wide Potential Window

S Zhao, Y Qin, X Wang, C Wang, X Chen, Y Wang… - Small, 2023 - Wiley Online Library
Electrochemical reduction of CO2 (CO2RR) into value‐added products is a promising
strategy to reduce energy consumption and solve environmental issues. Formic acid/formate …

Ampere-level CO2-to-formate electrosynthesis using highly exposed bismuth (110) facets modified with sulfur-anchored sodium cations

C Peng, S Yang, G Luo, S Yan, N Chen, J Zhang… - Chem, 2023 - cell.com
The high-rate electrosynthesis of formate from CO 2 is challenging due to the insufficient
active catalytic sites that can stabilize the∗ OCHO intermediate and suppress H 2 formation …

Anion-Mediated In Situ Reconstruction of the Bi2MoO6 Precatalyst for Enhanced Electrochemical CO2 Reduction over a Wide Potential Window

X Huang, X Han, R Tang, H Wu, S Chen… - … Applied Materials & …, 2023 - ACS Publications
Electrochemical CO2 reduction reaction (eCO2RR) is a viable approach to achieve carbon
neutrality. Bismuth-based electrocatalysts demonstrate exceptional selectivity in CO2-to …

Customizing catalyst surface/interface structures for electrochemical CO 2 reduction

X Tan, H Zhu, C He, Z Zhuang, K Sun, C Zhang… - Chemical …, 2024 - pubs.rsc.org
Electrochemical CO2 reduction reaction (CO2RR) provides a promising route to converting
CO2 into value-added chemicals and to neutralizing the greenhouse gas emission. For the …

Disentangling heterogeneous thermocatalytic formic acid dehydrogenation from an electrochemical perspective

X Qin, J Li, TW Jiang, XY Ma, K Jiang, B Yang… - Nature …, 2024 - nature.com
Heterogeneous thermocatalysis of formic acid dehydrogenation by metals in solution is of
great importance for chemical storage and production of hydrogen. Insightful understanding …

Boosting CO2 electroreduction to formate via bismuth oxide clusters

X Jiang, L Lin, Y Rong, R Li, Q Jiang, Y Yang, D Gao - Nano Research, 2023 - Springer
Supported metal (oxide) clusters, with both rich surface sites and high atom utilization
efficiency, have shown improved activity and selectivity for many catalytic reactions over …

Ce Promotion of In2O3 for Electrochemical Reduction of CO2 to Formate

T Wissink, FA Rollier, V Muravev, JMJJ Heinrichs… - ACS …, 2024 - ACS Publications
In2O3 is a promising electrocatalyst for CO2 electroreduction (CO2ER) to formate. In2O3
nanoparticles doped with Pd, Ni, Co, Zr, and Ce promoters using flame-spray pyrolysis were …