The high stability of the+ IVoxidation state limits thorium redox reactivity. Here we report the
synthesis and the redox reactivity of two Th (IV) complexes supported by the arene‐tethered …

Reduction of [{η5-1, 2, 4-(Me3Si) 3C5H2} 2UCl2](1) using potassium graphite (KC8) in the
presence of 2, 2′-bipyridine forms the uranium bipyridyl metallocene [{η5-1, 2, 4-(Me3Si) …

The uranium bipyridyl metallocene,[η5-1, 3-(Me3Si) 2C5H3] 2U (bipy)(2), is readily
accessible in good yield by adding potassium graphite (KC8) to a mixture of [η5-1, 3-(Me3Si) …

Early-actinide-based (U, Np, and Pu) single-molecule magnets (SMMs) have yet to show
magnetic properties similar to those of highly anisotropic lanthanide-based ones. However …

The uranium bipyridyl metallocene,[η5-1, 2, 4-(Me3C) 3C5H2] 2U (bipy)(2), prepared from
[η5-1, 2, 4-(Me3C) 3C5H2] 2UCl2 (1) and 2, 2′-bipyridine in the presence of potassium …

A family of thorium complexes featuring the redox-noninnocent pyridinediimine ligand
MesPDIMe was synthesized, including (MesPDIMe) ThCl4 (1-Th),(MesPDIMe) ThCl3 …

Attempted preparation of a low-valent Ca (I) complex by reduction of Ca iodide precursor
[LCaI (THF)] 2 (1)(L=[CH3C (NAr) CHC (CH3) NCH2CH2N (CH3) 2]−, Ar= 2, 6-i Pr2C6H3) …

The addition of potassium graphite (KC8) to a mixture of [η5-1, 3-(Me3C) 2C5H3] 2UCl2 (1)
and 2, 2′-bipyridine forms the uranium bipyridyl metallocene,[η5-1, 3-(Me3C) 2C5H3] 2U …

The reactivity of the thorium bipyridyl metallocene (Cp2 t Bu) 2Th (bipy)(1; Cp2 t Bu= η 5-1, 3-
(Me3C) 2C5H3) toward a series of small molecules was explored, and the emerging …

High-throughput screening rapidly tests an extensive array of chemical compounds to
identify hit compounds for specific biological targets in drug discovery. However, false …