The metathesis reactions, in their various versions, have become a powerful and extremely
valuable tool for the formation of carbon–carbon bonds in organic synthesis. The plethora of …

Olefin metathesis is an incredibly valuable transformation that has gained widespread use in
both academic and industrial settings. Lately, stereoretentive olefin metathesis has garnered …

Full control over the selectivity of carbon–carbon double-bond migrations would enable
access to stereochemically defined olefins that are central to the pharmaceutical, food …

The Z-alkene geometry is prevalent in various chemical compounds, including numerous
building blocks, fine chemicals, and natural products. Unfortunately, established Mo, W, and …

The efficient Z-selective cross-metathesis between acrylamides and common terminal
olefins has been developed by the use of novel cyclometalated ruthenium catalysts with …

Nitriles are found in many bioactive compounds, and are among the most versatile
functional groups in organic chemistry. Despite many notable recent advances, however …

In situ methylene capping is introduced as a practical and broadly applicable strategy that
can expand the scope of catalyst-controlled stereoselective olefin metathesis considerably …

Ruthenium dithiolene complexes, particularly the dithiocatecholates Ru (S2C6H2-3, 6-
Cl2)(NHC)(= CHC6H4-2-O i Pr)(NHC= H2IPr, H2IMes), are an important class of olefin …

A series of neutral molybdenum imido alkylidene N-heterocyclic carbene (NHC) bistriflate
and monotriflate monoalkoxide complexes as well as cationic molybdenum imido alkylidene …

Non‐directed regioselective activation of bis (boronic esters), followed by functionalization,
is reported. A bulky activator is shown to selectively activate the less hindered boronic ester …