Claisen rearrangement over the past nine decades

AM Martín Castro - Chemical Reviews, 2004 - ACS Publications
The discovery of the Claisen rearrangement almost a century ago1 offered a potentially
useful synthetic tool to the organic chemist. Over the decades this usefulness has been …

Polyene natural products

C Thirsk, A Whiting - Journal of the Chemical Society, Perkin …, 2002 - pubs.rsc.org
Polyene natural products - Journal of the Chemical Society, Perkin Transactions 1 (RSC
Publishing) DOI:10.1039/B109741P Royal Society of Chemistry View PDF VersionPrevious …

Boron science

NS Hosmane - New technologies and applications, 2011 - api.taylorfrancis.com
What is boron? The question itself may not seem very significant to many people. Their
introduction to the word “boron” could come as the butt of a joke. Conan O'Brien made jokes …

Selective monodeprotection of bis-silyl ethers

RD Crouch - Tetrahedron, 2004 - Elsevier
As synthetic targets have grown more complex, protection/deprotection protocols have
assumed prominent roles in synthetic organic chemistry. 1–3 The ability to efficiently protect …

Fostriecin: chemistry and biology

DS Lewy, C Gauss, DR Soenen… - Current medicinal …, 2002 - ingentaconnect.com
A review of the current status of the chemistry and biology of fostriecin (CI-920) is provided.
Fostriecin is a structurally unique, naturally-occurring phosphate monoester that exhibits …

Total Synthesis of Fostriecin (CI‐920)

DE Chavez, EN Jacobsen - Angewandte Chemie, 2001 - Wiley Online Library
Fostriecin (CI-920, 1; see Scheme1) is a structurally interesting antitumor agent that was first
isolated in 1983 by scientists at Warner Lambert-Parke Davis.[1] It displays in vitro activity …

From Allylic Sulfoxides to Allylic Sulfenates: Fifty Years of a Never-Ending [2, 3]-Sigmatropic Rearrangement

I Colomer, M Velado… - Chemical …, 2017 - ACS Publications
The [2, 3]-sigmatropic rearrangement of allylic sulfoxides to allylic sulfenates is a reversible
process, generally shifted toward the sulfoxide. In the presence of thiophiles, the sulfenate is …

Highly satisfactory alkynylation of alkenyl halides via Pd-catalyzed cross-coupling with alkynylzincs and its critical comparison with the Sonogashira alkynylation

E Negishi, M Qian, F Zeng, L Anastasia… - Organic Letters, 2003 - ACS Publications
The Pd-catalyzed alkynylation of various alkenyl halides and triflates with alkynylzincs
proceeds well even with alkynyl derivatives containing electron-withdrawing groups. The …

Formal catalytic asymmetric total synthesis of fostriecin

K Fujii, K Maki, M Kanai, M Shibasaki - Organic Letters, 2003 - ACS Publications
Formal Catalytic Asymmetric Total Synthesis of Fostriecin | Organic Letters ACS ACS Publications
C&EN CAS Find my institution Log In Organic Letters ACS Publications. Most Trusted. Most …

Exploiting hidden symmetry in natural products: Total syntheses of amphidinolides C and F

S Mahapatra, RG Carter - Journal of the American Chemical …, 2013 - ACS Publications
The total synthesis of amphidinolide C and a second-generation synthesis of amphidinolide
F have been accomplished through the use of a common intermediate to access both the C1 …