Scrutinizing low-spin Cr (II) complexes

CC Scarborough, S Sproules, CJ Doonan… - Inorganic …, 2012 - ACS Publications
The oxidation state of the chromium center in the following compounds has been probed
using a combination of chromium K-edge X-ray absorption spectroscopy and density …

Combining NMR of dynamic and paramagnetic molecules: fluxional high-spin nickel (II) complexes bearing bisguanidine ligands

P Roquette, A Maronna, M Reinmuth, E Kaifer… - Inorganic …, 2011 - ACS Publications
A detailed nuclear magnetic resonance (NMR) study was carried out on a series of
paramagnetic, tetrahedrally coordinated nickel (II) dihalide complexes featuring chelating …

Polyhedral boron cage compounds: An account

NS Hosmane, JA Maguire, Z Yinghuai - Main Group Chemistry, 2007 - Taylor & Francis
An account of recent research on the syntheses, structures, and properties of the complexes
formed between carboranes and metals in the pentagonal bipyramidal and icosahedral …

Evolution of C2B4 Carborane Chemistry:  from Early Years to the Present

NS Hosmane, JA Maguire - Organometallics, 2005 - ACS Publications
A review of the chemistry of polyhedral cluster complexes in which s-, p-, d-and f-block
metals are incorporated mainly into C cage-trimethylsilyl-substituted C2B4 carborane cages …

Pentadienyls vs Cyclopentadienyls and Reversal of Metal− Ligand Bonding Affinity with Metal Oxidation State: Synthesis, Molecular Structures, and Electronic …

A Rajapakshe, NE Gruhn… - Journal of the …, 2004 - ACS Publications
Molecules of the form Cp (6, 6-dmch) ZrX2 (Cp= η5-cyclopentadienyl, X= Cl, Br, I; 6, 6-
dmch= η5-6, 6-dimethylcyclohexadienyl) have been synthesized, and the molecular and …

Vanadium organometallics

C Lorber - Reference Module in Chemistry, Molecular Sciences …, 2015 - hal.science
This review surveys the organometallic chemistry of vanadium during the period 1993-2014.
It is an updated version of the" Vanadium" chapter in COMC-III (2007) that originally covered …

Advances in the metallacarborane chemistry of f-block elements

R Satapathy, BP Dash, JA Maguire… - Dalton Transactions, 2010 - pubs.rsc.org
The role of carborane clusters in organometallic chemistry is diverse. A number of carborane
cage systems such as C2B4, C2B9 and C2B10 clusters have been extensively used for the …

Delocalized and localized donating–accepting Mn–C interactions in half-sandwich cyclopentadienyl and pentadienyl complexes

J Solís-Huitrón, N Zúñiga-Villarreal… - Dalton …, 2017 - pubs.rsc.org
The widely used cyclopentadienyl (Cp) ligand and the pentadienyl (Pdl) ligand have very
similar molecular orbitals (MOs) but they have significantly different chemical behavior. The …

Heteropentadienyl Analogues of Half-Open Ruthenocenes: Metal− Ligand Interactions and Electronic Structure Perturbations

A Rajapakshe, MA Paz-Sandoval, JA Gutierrez… - …, 2006 - ACS Publications
The electronic structures of molecules of the form Cp* Ru (η5-Pdl)(where Cp*= η5-
pentamethylcyclopentadienyl and Pdl= 2, 4-dimethylpentadienyl and various …

Novel Sandwich Complexes of Terbium and Erbium Metals Derived from Mixed η5 Open-Pentadienyl and C2B4 Carborane Ligands:  A Synthetic and Structural …

A Li, J Wang, C Zheng, JA Maguire… - Organometallics, 2004 - ACS Publications
Mixed-ligand dimeric lanthanacarboranes of the type [(η5-2, 4-(Me) 2C5H5)(η5-2, 3-(Me3Si)
2-2, 3-C2B4H4) Ln] 2 (Ln= Tb (2), Er (3)) were prepared as orange and yellow crystalline …