Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …

Palladium-catalyzed cross-coupling reactions have emerged as one of the most versatile
tools in organic chemistry. Extensive efforts were made to adapt these reactions to aqueous …

An abnormal N‐heterocyclic carbene (aNHC) based homogeneous catalyst has been used
for the reduction of carbon dioxide to methoxyborane in the presence of a range of …

A base-metal, Fe (0)-catalyzed hydrosilylation of imines to obtain amines is reported here
which outperforms its noble-metal congeners with the highest TON of 17000. The catalyst,(a …

Herein we report the synthesis of a nickel (II) dichloro complex bearing an abnormal N-
heterocyclic carbene (aNHC). The NiCl2 (aNHC) 2 complex has been used as an efficient …

[(c AAC) Fe (CO) 4](1) catalyzed head-to-head dimerization of terminal arylalkynes toward
conjugated enynes in very high yield and high E selectivity (up to 84: 16 E: Z). The protocol …

Herein we report the hydroheteroarylation of vinylarenes with benzoxazole in the presence
of a free abnormal N-heterocyclic carbene and Ni (COD) 2, resulting in 1, 1-diarylethane …

A novel, Pd-catalyzed oxidative Heck reaction of non-activated alkenes synergistically
directed by bifunctional groups has been developed firstly by using O2 as a green oxidant …

Abstract N‐bromosuccinimide (NBS)‐mediated one‐pot, green, efficient and practical
synthesis of substituted imidazoles and quinoxalines has been achieved by the reaction of …

Aromatic triangular tri‐palladium cations 1–3, abbreviated as [Pd3]+, have shown interesting
photoelectric properties, Lewis basic character, and excellent activities in catalytic …