Recent progress on cyano-bridged transition-metal-based single-molecule magnets and single-chain magnets

JH Wang, ZY Li, M Yamashita, XH Bu - Coordination Chemistry Reviews, 2021 - Elsevier
Novel functional molecular-based magnetic materials, especially some members of the
Prussian blue family, have gained significant attention over the past few decades as they …

Dicyanometalate chemistry: A type of versatile building block for the construction of cyanide-bridged molecular architectures

S Wang, XH Ding, YH Li, W Huang - Coordination Chemistry Reviews, 2012 - Elsevier
Cyanide-bridged molecule-based magnetic materials with reduced dimensionality, such as
single-molecule magnets (SMMs) and single-chain magnets (SCMs), have attracted great …

Substituent effects on exchange coupling and magnetic relaxation in 2, 2′-bipyrimidine radical-bridged dilanthanide complexes

CA Gould, E Mu, V Vieru, LE Darago… - Journal of the …, 2020 - ACS Publications
Systematic analysis of related compounds is crucial to the design of single-molecule
magnets with improved properties, yet such studies on multinuclear lanthanide complexes …

Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical Communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

Material applications for salen frameworks

SJ Wezenberg, AW Kleij - Angewandte Chemie International …, 2008 - Wiley Online Library
Salens are among the most widely studied ligands in chemistry. They are primarily applied
in homogeneous catalysis, a use that helps to increase our knowledge of environmentally …

Chiral Cyanide-Bridged CrIII–MnIII Heterobimetallic Chains Based on [(Tp)Cr(CN)3]: Synthesis, Structures, and Magnetic Properties

MX Yao, Q Zheng, XM Cai, YZ Li, Y Song… - Inorganic …, 2012 - ACS Publications
By the reactions of MnIII Schiff-base complexes with the tricyanometalate building block,[(Tp)
Cr (CN) 3]−(Tp= Tris (pyrazolyl) hydroborate), two couples of enantiomerically pure chiral …

Self-assembled synthesis, characterization and antimicrobial activity of zinc (II) salicylaldimine complexes

MT Kaczmarek, R Jastrząb, E Hołderna-Kędzia… - Inorganica Chimica …, 2009 - Elsevier
One-pot metal promoted reactions between salicylaldehyde and 4-methyl-1, 3-
phenylenediamine in the presence of metal salts acting as template agents yield zinc (II) …

Methods and models of theoretical calculation for single-molecule magnets

QC Luo, YZ Zheng - Magnetochemistry, 2021 - mdpi.com
Theoretical calculation plays an important role in the emerging field of single-molecule
magnets (SMMs). It can not only explain experimental phenomena but also provide synthetic …

Trigonal-Bipyramidal metal cyanide complexes: A versatile platform for the systematic assessment of the magnetic properties of prussian blue materials

KE Funck, MG Hilfiger, CP Berlinguette… - Inorganic …, 2009 - ACS Publications
Pentanuclear cyanide-bridged clusters of the general formula {[M (tmphen) 2] 3 [M′(CN) 6]
2}(tmphen= 3, 4, 7, 8-tetramethyl-1, 10-phenanthroline) have been under investigation in our …

Pre-programmed self-assembly of polynuclear clusters

T Shiga, GN Newton, H Oshio - Dalton Transactions, 2018 - pubs.rsc.org
This perspective reviews our recent efforts towards the self-assembly of polynuclear clusters
with ditopic and tritopic multidentate ligands HL1 (2-phenyl-4, 5-bis {6-(3, 5-dimethylpyrazol …