Apoptosis shapes development and differentiation, has a key role in tissue homeostasis, and is deregulated in cancer. In most cases, successful apoptosis is triggered by …
Recent advances in enzyme engineering and design have expanded nature's catalytic repertoire to functions that are new to biology,,. However, only a subset of these engineered …
Cytochrome c (cyt c) is a small soluble heme protein characterized by a relatively flexible structure, particularly in the ferric form, such that it is able to sample a broad conformational …
The metal centres in metalloenzymes and molecular catalysts are responsible for the rearrangement of atoms and electrons during complex chemical reactions, and they enable …
X-ray spectroscopy has had a significant and continually growing impact on catalysis research for nearly 50 years. In particular, the ability to obtain element selective electronic …
S Lafuerza, A Carlantuono, M Retegan… - Inorganic …, 2020 - ACS Publications
K-fluorescence X-ray emission spectroscopy (XES) is receiving growing interest in all fields of natural sciences to investigate the local spin. The spin sensitivity in Kβ (Kα) XES stems …
The non-equilibrium dynamics of electrons and nuclei govern the function of photoactive materials. Disentangling these dynamics remains a critical goal for understanding …
KJ Gaffney - Chemical Science, 2021 - pubs.rsc.org
Light-driven chemical transformations provide a compelling approach to understanding chemical reactivity with the potential to use this understanding to advance solar energy and …
Biological systems provide attractive reactivity blueprints for the design of challenging chemical transformations. Emulating the operating mode of natural systems may however …