First-row transition-metal-mediated reactions constitute an important and growing area of
research due to the low cost, low toxicity, and exceptional synthetic versatility of these …

Covering: up to 2022 Pyrroloindoline is a privileged tricyclic indoline motif widely present in
many biologically active and medicinally valuable natural products. Thus, understanding the …

Oxidative rearrangement of 3-substituted indoles is a fundamental organic transformation for
the synthesis of 2-oxindole scaffolds. However, this time-consuming and complex task …

Nitroxides can absorb both ultraviolet (UV) and visible light, and their electron can be
excited from the π-bonding orbital to the antibonding π* orbital or the n-bonding orbital to the …

Covering up to 2021 Complex cyclotryptamine alkaloids with a bispyrrolidino [2, 3-b]
indoline (BPI) skeleton are an intriguing family of natural products, exhibiting wide …

Herein, we report an unprecedented skeletal rearrangement reaction of tetrahydro‐β‐
carbolines enabled by copper‐catalyzed single‐electron oxidative oxygenation, in which …

We report a safe and convenient open-flask copper-catalyzed selective oxidation/
functionalization methodology for tetrahydrocarbolines and tetrahydro-β-carbolines that …

We report a general copper/iodine co-catalyzed oxygenative transannulation strategy using
readily available tryptamines. Molecular oxygen and water are used as oxygen sources and …

Biomimetic oxidative dimerization of tryptophan derivatives in aqueous media with oxygen
as a bulk oxidant catalyzed by an iron octacarboxy phthalocyanine complex was …

The concise, enantioselective total syntheses of (+)-asperazine (1),(+)-iso-pestalazine A (2),
and (+)-pestalazine A (3) have been achieved by the development of a late-stage C3–C8 …