Enhancing blocking temperature (TB) is one of the holy grails in Single Molecule Magnets (SMMs), as any future potential application in this class of molecules is directly correlated to …
YN Guo, GF Xu, W Wernsdorfer, L Ungur… - Journal of the …, 2011 - ACS Publications
The high axiality and Ising exchange interaction efficiently suppress quantum tunneling of magnetization of an asymmetric dinuclear DyIII complex, as revealed by combined …
A series of five isostructural tetranuclear lanthanide complexes of formula [Ln4 (μ3-OH) 2 (mdeaH) 2 (piv) 8],(mdeaH2= N-methyldiethanolamine; piv= pivalate; Ln= Tb (1), Dy (2), Ho …
V Mereacre, AM Ako, R Clérac… - … A European Journal, 2008 - Wiley Online Library
The reaction of [Mn6O2 (Piv) 10 (4‐Me‐py) 2.5 (PivH) 1.5](1)(py: pyridine, Piv: pivilate) with N‐methyldiethanolamine (mdeaH2) and Ln (NO3) 3⋅ 6 H2O in MeCN leads to a series of …
Y Peng, AK Powell - Coordination Chemistry Reviews, 2021 - Elsevier
The most studied examples of 3d-4f based single molecule magnets (SMMs) and their coordination cluster counterparts is that of the 3d-4f butterfly systems which provide a test …
IR Jeon, R Clérac - Dalton transactions, 2012 - pubs.rsc.org
The field of molecular magnetism has rapidly expanded since the discovery of single- molecule magnets (SMMs) at the beginning of the 1990s. Numerous SMMs have been …
H Miyasaka, K Nakata, L Lecren… - Journal of the …, 2006 - ACS Publications
Three two-dimensional (2D) network compounds based on MnIII/MnII tetranuclear single- molecule magnets (SMMs) connected by dicyanamide (dcn-) linkers have been …
GJ Chen, CY Gao, JL Tian, J Tang, W Gu, X Liu… - Dalton …, 2011 - pubs.rsc.org
By changing the ratio of reactants, two mononuclear Dy complexes,[Dy (phen)(acac) 3](1) and [Dy (phen) 2 (NO3) 2 (acac)]· H2O (2) have been synthesized and structurally …