Structural aspects affecting phase selection in inorganic zeolite synthesis

K Asselman, D Vandenabeele, N Pellens… - Chemistry of …, 2022 - ACS Publications
A guideline for zeolite phase selection in inorganic synthesis media is proposed, based on a
systematic exploration of synthesis from inorganic media using liquid Na+, K+, and Cs+ …

[HTML][HTML] Synthesis of zeolites using kaolin in concentrated sodium hydroxide-aluminate solutions

J Vogrin, T Santini, H Peng, L Zhao, J Vaughan - Applied Clay Science, 2023 - Elsevier
The synthesis of zeolites through the hydrothermal treatment of kaolin presents a cost-
effective and sustainable method of production, however, the phases which remain stable in …

Does water enable porosity in aluminosilicate zeolites? Porous frameworks versus dense minerals

K Asselman, M Haouas, M Houlleberghs… - Crystal Growth & …, 2023 - ACS Publications
Recently identified zeolite precursors consisting of concentrated, hyposolvated
homogeneous alkalisilicate liquids, hydrated silicate ionic liquids (HSIL), minimize …

Polysilicate Porous Organic Polymers (PSiPOPs), a Family of Porous, Ordered 3D Reticular Materials with Polysilicate Nodes and Organic Linkers

J Jamoul, S Smet, S Radhakrishnan… - Chemistry of …, 2024 - ACS Publications
Spherosilicate, consisting of a double 4-ring cyclosilicate core (D4R; Si8O20) with every
corner functionalized with a dimethylsilyl chloride group (-SiMe2Cl), was used as a node to …

Simple Molecular Model for Hydrated Silicate Ionic Liquids, a Realistic Zeolite Precursor

J Vekeman, D Vandenabeele… - Chemistry of …, 2024 - ACS Publications
Despite the widespread use of zeolites in the chemical industry, their formation process is
not fully understood due to the complex and heterogeneous structure of traditional synthesis …

How Water and Ion Mobility Affect the NMR Fingerprints of the Hydrated JBW Zeolite: A Combined Computational‐Experimental Investigation

S Vanlommel, AEJ Hoffman, S Smet… - … A European Journal, 2022 - Wiley Online Library
An important aspect within zeolite synthesis is to make fully tunable framework materials
with controlled aluminium distribution. A major challenge in characterising these zeolites at …

Can the combination of in situ differential impedance spectroscopy and 27Al NMR detect incongruent zeolite crystallization?

D Vandenabeele, N Doppelhammer… - Microporous and …, 2024 - Elsevier
Crystallizing zeolites with isotropic properties is critical to the chemical industry but can be
extremely challenging as small deviations in the synthesis conditions can have extreme …

Revisiting the synthesis of gibbsite, a precursor for Li/Al LDH synthesis and its use as a support for porphyrin immobilization

G Bosa, CG Silva, BR Brito, CM Terzi… - Journal of the Brazilian …, 2024 - SciELO Brasil
In this work, some of the synthesis methods already reported for aluminum (III) hydroxide
polymorphs with layered structure like gibbsite are revisited. Gibbsite was synthesized with …