Palladium catalysed cross-couplings reactions have been a dominant method in synthetic
chemistry for decades. Despite this, the role of the solvent is often taken for granted and …

1.1. General Considerations Palladium catalysis is one of the most important synthetic tools
in modern organic synthesis. A particularly attractive synthetic feature of palladium catalysis …

Collectively, palladium‐catalyzed coupling reactions represent some of the most powerful
and versatile tools available to synthetic organic chemists. Their widespread popularity …

Homogeneous palladium catalysis has gained enormous relevance in various coupling
reactions such as Heck, Stille, Suzuki, Sonogashira, and Buchwald-Hartwig reactions. Many …

A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki
coupling reactions over the last 15 years. Historically, nearly every form of palladium used …

Bernard Shaw's pioneering research1-15 on cyclometalated phosphine-based pincer
complexes has inspired many others. 16-208 Although the first metal complexes with …

Since the first reports in the late 1970s on transition metal complexes containing pincer‐type
ligands—named after the particular coordination mode of these ligands—these systems …

This review describes the recent advances in understanding of the mechanism of palladium
catalyzed C–C cross-coupling reactions. The discussion is focused on the role of palladium …

Pincer complexes are useful tools for organic synthesis. Their high stability and easy
functionalization have allowed the development of novel catalytic systems that have had a …

Palladium-catalyzed bond-forming processes (eg, CC, CX, CY; X) F; Y) NR2, OR, SR, etc.)
represent essential tools for the synthetic chemist. A fascinating myriad of adventurous and …