R Kumar, P Dimitrov, KJ Bartelson, J Emert… - …, 2012 - ACS Publications
The carbocationic polymerization of isobutylene (IB), co-initiated by GaCl3 or FeCl3· dialkyl ether 1: 1 complexes has been investigated in hexanes in the− 20 to 10° C temperature …
P Dimitrov, J Emert, R Faust - Macromolecules, 2012 - ACS Publications
The carbocationic polymerization of isobutylene (IB), co-initiated by AlCl3/ether complexes, has been reexamined and extended to different dialkyl ethers. In the absence of a proton …
P Dimitrov, J Emert, J Hua, S Keki, R Faust - Macromolecules, 2011 - ACS Publications
The complex mechanism of the carbocationic rearrangements leading to a variety of olefin (exo-, endo-, tri-, and tetra-substituted) end groups in the cationic polymerization of …
Cationic polymerization of isobutylene (IB) in the presence of other C4 olefins, 1-butene (B1), cis-2-butene (C2B), and 1, 3-butadiene (BD) using the ethylaluminum dichloride …
VA Rozentsvet, VG Kozlov, NA Korovina… - Macromolecular …, 2014 - Wiley Online Library
A novel method for the investigation of the chain‐end structure of poly (1, 3‐pentadiene) s synthesized using the CF3COOD/TiCl4 initiating system is developed. It is shown for the first …
P De, R Faust - … Precise Synthesis to Macroscopic Materials and …, 2022 - Wiley Online Library
Macromolecular engineering is defined as the total synthesis of tailor‐made macromolecules. The ultimate goal of this technology is to obtain a high degree of control …
P Sigwalt, M Moreau - Macromolecular Symposia, 2011 - Wiley Online Library
The reactivity ratios r1 and r2 in copolymerizations of styrene and parasubstituted styrenes, for which r1= 1/r2, are in contradiction with diffusion control for their propagation reactions …
P Sigwalt, JP Vairon - Polimery, 2014 - ichp.vot.pl
This short review aims at reconsidering the behaviours of a few vinyl monomers (isobutylvinylether, p-methylstyrene, p-methoxystyrene, indene and 2, 4, 6-trimethylstyrene) …
H Bouchékif, AJ Amass - Macromolecular Symposia, 2011 - Wiley Online Library
The activation‐deactivation pseudo‐equilibrium coefficient Qt and constant K0 (= Qt x PaT1, t=([A1] x [Ox])/([T1] x [T])) as well as the factor of activation (PaT1, t) and rate constants of …