Resonance-stabilised hydrocarbon radicals serve as reaction intermediates in flames,
plasmas, atmospheres and interstellar space. Their stability is conferred by delocalisation of …

Using a combination of resonant two-photon two-color ionization (R2C2PI) and laser-
induced fluorescence/dispersed fluorescence spectroscopy, we have examined the A~ 2 A …

The hydrogen-atom adduct with anthracene, 9-dihydroanthracenyl radical (C14H11), and its
deuterated analogue have been identified by laser spectroscopy coupled to time-of-flight …

Important recent experimental studies have allowed the isomer-selective identification of the
2-, 3-, and 4-picolyl radicals. The picolyl radicals and their valence isoelectronic P, As, Sb …

We apply a combination of state-of-the-art experimental and quantum-chemical methods to
elucidate the electronic and chemical energetics of hydrogen adduction to a model open …

Excitation spectra of the 1H-naphthalene (1-C10H9) and 1D-naphthalene (1-C10H8D)
radicals, and their cations, are obtained by laser spectroscopy and mass spectrometry of a …

The reaction of H+ phenol and H/D+ toluene has been studied in a supersonic expansion
after electric discharge. The (1+ 1′) resonance-enhanced multiphoton ionization (REMPI) …

Biomimetic models of short‐lived enzymatic reaction intermediates can give useful insight
into the properties and coordination chemistry of transition metal complexes. In this work, we …

We report the spectroscopic observation of the jet-cooled para-ethynylbenzyl (PEB) radical,
a resonance-stabilized isomer of C9H7. The radical was produced in a discharge of p …

In this chapter we will review the processes at play in the excited states of protonated
molecules. More specifically, the discussion will be restricted to aromatic molecules, on …