Glass transition of polymers in bulk, confined geometries, and near interfaces

S Napolitano, E Glynos, NB Tito - Reports on Progress in Physics, 2017 - iopscience.iop.org
When cooled or pressurized, polymer melts exhibit a tremendous reduction in molecular
mobility. If the process is performed at a constant rate, the structural relaxation time of the …

Confined crystallization of polymeric materials

RM Michell, AJ Müller - Progress in Polymer Science, 2016 - Elsevier
The interest in confined crystallization has greatly increased with the development and
progress of nanotechnology applications. Polymeric confined crystallization has been …

Vertically aligned and continuous nanoscale ceramic–polymer interfaces in composite solid polymer electrolytes for enhanced ionic conductivity

X Zhang, J Xie, F Shi, D Lin, Y Liu, W Liu, A Pei… - Nano …, 2018 - ACS Publications
Among all solid electrolytes, composite solid polymer electrolytes, comprised of polymer
matrix and ceramic fillers, garner great interest due to the enhancement of ionic conductivity …

Confined crystallization of polymers within nanopores

G Liu, AJ Muller, D Wang - Accounts of Chemical Research, 2021 - ACS Publications
Conspectus Crystallization of polymeric materials under nanoscopic confinement is highly
relevant for nanotechnology applications. When a polymer is confined within rigid …

[HTML][HTML] Fractionated crystallization in semicrystalline polymers

L Sangroniz, B Wang, Y Su, G Liu, D Cavallo… - Progress in Polymer …, 2021 - Elsevier
The crystallization of heterogeneously nucleated bulk polymers typically occurs in a single
exothermic process, within a narrow temperature range, ie, a single exothermic peak is …

[HTML][HTML] Confinement effects on polymer crystallization: From droplets to alumina nanopores

RM Michell, I Blaszczyk-Lezak, C Mijangos, AJ Müller - Polymer, 2013 - Elsevier
We review previous works on polymer confined crystallization employing strategies that
allow confinement to go from the micron to the nanometer scale: droplets, blends, block …

Electronic effects of nano-confinement in functional organic and inorganic materials for optoelectronics

J Ko, R Berger, H Lee, H Yoon, J Cho… - Chemical Society …, 2021 - pubs.rsc.org
When various optically and/or electronically active materials, such as conjugated polymers,
perovskites, metals, and metal oxides, are confined at the nanoscale, they can exhibit …

Interfacial energy and glass temperature of polymers confined to nanoporous alumina

S Alexandris, P Papadopoulos, G Sakellariou… - …, 2016 - ACS Publications
We report on the effect of interfacial energy on the glass temperature, T g, of several
amorphous polymers with various glass temperatures and polymer/substrate interactions …

Molecular self-assembly of one-dimensional polymer nanostructures in nanopores of anodic alumina oxide templates

H Wu, Y Higaki, A Takahara - Progress in Polymer Science, 2018 - Elsevier
Abstract One-dimensional (1-D) polymer nanostructures have attracted much attention due
to their unique properties and many potential applications in areas such as sensors …

Crystallization, orientation, and solid–solid crystal transition of polybutene-1 confined within nanoporous alumina

G Shi, Z Wang, M Wang, G Liu, D Cavallo… - …, 2020 - ACS Publications
The effect of confinement on the crystallization, crystal orientation, and polymorphic crystal
transition of bulk and infiltrated polybutene-1 (PB-1) within anodic aluminum oxide (AAO) …