The metal centres in metalloenzymes and molecular catalysts are responsible for the
rearrangement of atoms and electrons during complex chemical reactions, and they enable …

One major challenge of future sustainable photochemistry is to replace precious and rare
transition metals in applications such as energy conversion or electroluminescence by earth …

There is a long-standing interest in iron (II) complexes that emit from metal-to-ligand charge
transfer (MLCT) excited states, analogous to ruthenium (II) polypyridines. The 3d6 electrons …

Quintet oxoiron (IV) intermediates are often invoked in nonheme iron enzymes capable of
performing selective oxidation, while most well-characterized synthetic model oxoiron (IV) …

Examples of Fe complexes with long-lived (≥ 1 ns) charge-transfer states are limited to
pseudo-octahedral geometries with strong σ-donor chelates. Alternative strategies based on …

Developing efficient cyan‐green phosphors and ultrathin phosphor‐glass composites
(PGCs) with remarkable chemical and thermal stability is important for fabricating full‐visible …

The ability to access panchromatic absorption and long-lived charge-transfer (CT) excited
states is critical to the pursuit of abundant-metal molecular photosensitizers. Fe (II) …

The ultrafast dynamical response of solute–solvent interactions plays a key role in transition
metal complexes, where charge transfer states are ubiquitous. Nonetheless, there exist very …

Reliably identifying short-lived chemical reaction intermediates is crucial to elucidate
reaction mechanisms but becomes particularly challenging when multiple transient species …

Owing to their light-harvesting properties, nickel–bipyridine (bpy) complexes have found
wide use in metallaphotoredox cross-coupling reactions. Key to these transformations are Ni …