[HTML][HTML] Uranium: the nuclear fuel cycle and beyond

BMT Costa Peluzo, E Kraka - International Journal of Molecular Sciences, 2022 - mdpi.com
This review summarizes the recent developments regarding the use of uranium as nuclear
fuel, including recycling and health aspects, elucidated from a chemical point of view, ie …

Diverse uses of the reaction of frustrated Lewis pair (FLP) with hydrogen

DW Stephan - Journal of the American Chemical Society, 2021 - ACS Publications
The articulation of the notion of “frustrated Lewis pairs”(FLPs) emerged from the discovery
that H2 can be reversibly activated by combinations of sterically encumbered main group …

From chemical curiosities and trophy molecules to uranium-based catalysis: developments for uranium catalysis as a new facet in molecular uranium chemistry

DR Hartline, K Meyer - Jacs Au, 2021 - ACS Publications
Catalysis remains one of the final frontiers in molecular uranium chemistry. Depleted
uranium is mildly radioactive, continuously generated in large quantities from the production …

[HTML][HTML] Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis

J Du, JA Seed, VEJ Berryman, N Kaltsoyannis… - Nature …, 2021 - nature.com
Determining the nature and extent of covalency of early actinide chemical bonding is a
fundamentally important challenge. Recently, X-ray absorption, electron paramagnetic, and …

[HTML][HTML] Photochemical synthesis of transition metal-stabilized uranium (VI) nitride complexes

X Xin, I Douair, T Rajeshkumar, Y Zhao, S Wang… - Nature …, 2022 - nature.com
Uranium nitrides play important roles in dinitrogen activation and functionalization and in
chemistry for nuclear fuels, but the synthesis and isolation of the highly reactive uranium (VI) …

A thiolate-bridged FeIVFeIV μ-nitrido complex and its hydrogenation reactivity toward ammonia formation

Y Zhang, J Zhao, D Yang, B Wang, Y Zhou, J Wang… - Nature Chemistry, 2022 - nature.com
Iron nitrides are key intermediates in biological nitrogen fixation and the industrial Haber–
Bosch process, used to form ammonia from dinitrogen. However, the proposed successive …

Advances in electrochemical transformation of N2 using molecular catalysts

Q Yuan, J Wei, D Deng, ZJ Shi, P Chen, Z Xi - Science China Chemistry, 2023 - Springer
The conversion of N2 to NH3 holds great importance due to the essential role of NH3 in
fertilizer production, energy storage and the synthesis of key industrial chemicals …

[HTML][HTML] Progress in the chemistry of molecular actinide-nitride compounds

M Keener, L Maria, M Mazzanti - Chemical Science, 2023 - pubs.rsc.org
The chemistry of actinide-nitrides has witnessed significant advances in the last ten years
with a large focus on uranium and a few breakthroughs with thorium. Following the early …

Indentation-strain stiffening in tungsten nitrides: Mechanisms and implications

C Lu, C Chen - Physical Review Materials, 2020 - APS
We report on a systematic computational study of ideal strengths, ie, the lowest stresses
needed to destabilize a perfect crystal under a variety of loading conditions for six stable and …

Surface passivation induced a significant enhancement of superconductivity in layered two-dimensional MSi 2 N 4 (M= Ta and Nb) materials

L Yan, BT Wang, X Huang, Q Li, K Xue, J Zhang… - Nanoscale, 2021 - pubs.rsc.org
Two-dimensional (2D) transition metal di-nitrides (TMN2) have been arousing great interest
for their unique mechanic, electronic, optoelectronic, and magnetic properties. The recent …