Understanding polaritonic chemistry from ab initio quantum electrodynamics

M Ruggenthaler, D Sidler, A Rubio - Chemical Reviews, 2023 - ACS Publications
In this review, we present the theoretical foundations and first-principles frameworks to
describe quantum matter within quantum electrodynamics (QED) in the low-energy regime …

[HTML][HTML] Cavity quantum materials

F Schlawin, DM Kennes, MA Sentef - Applied Physics Reviews, 2022 - pubs.aip.org
The emergent field of cavity quantum materials bridges collective many-body phenomena in
solid state platforms with strong light–matter coupling in cavity quantum electrodynamics …

[图书][B] The Jaynes–Cummings model and its descendants: modern research directions

J Larson, T Mavrogordatos - 2021 - iopscience.iop.org
The Jaynes–Cummings Model (JCM) has recently been receiving increased attention as
one of the simplest, yet intricately nonlinear, models of quantum physics. Emphasising the …

[HTML][HTML] A perspective on ab initio modeling of polaritonic chemistry: The role of non-equilibrium effects and quantum collectivity

D Sidler, M Ruggenthaler, C Schäfer… - The Journal of …, 2022 - pubs.aip.org
This Perspective provides a brief introduction into the theoretical complexity of polaritonic
chemistry, which emerges from the hybrid nature of strongly coupled light–matter states. To …

Making ab initio QED functional (s): Nonperturbative and photon-free effective frameworks for strong light–matter coupling

C Schäfer, F Buchholz, M Penz… - Proceedings of the …, 2021 - National Acad Sciences
Strong light–matter coupling provides a promising path for the control of quantum matter
where the latter is routinely described from first principles. However, combining the …

Strong coupling in chiral cavities: nonperturbative framework for enantiomer discrimination

RR Riso, L Grazioli, E Ronca, T Giovannini, H Koch - Physical Review X, 2023 - APS
The development of efficient techniques to distinguish mirror images of chiral molecules
(enantiomers) is very important in both chemistry and physics. Enantiomers share most …

Cavity light-matter entanglement through quantum fluctuations

G Passetti, CJ Eckhardt, MA Sentef, DM Kennes - Physical Review Letters, 2023 - APS
The hybridization between light and matter forms the basis to achieve cavity control over
quantum materials. In this Letter we investigate a cavity coupled to a quantum chain of …

Weakened topological protection of the quantum Hall effect in a cavity

V Rokaj, J Wang, J Sous, M Penz, M Ruggenthaler… - Physical Review Letters, 2023 - APS
We study the quantum Hall effect in a two-dimensional homogeneous electron gas coupled
to a quantum cavity field. As initially pointed out by Kohn, Galilean invariance for a …

Polaritonic Hofstadter butterfly and cavity control of the quantized Hall conductance

V Rokaj, M Penz, MA Sentef, M Ruggenthaler, A Rubio - Physical Review B, 2022 - APS
In a previous work [Rokaj, Phys. Rev. Lett. 123, 047202 (2019) 0031-9007
10.1103/PhysRevLett. 123.047202] a translationally invariant framework called quantum …

Vacuum-induced symmetry breaking of chiral enantiomer formation in chemical reactions

Y Ke, Z Song, QD Jiang - Physical Review Letters, 2023 - APS
A material with symmetry breaking inside can transmit the symmetry breaking to its vicinity
by vacuum electromagnetic fluctuations. Here, we show that vacuum quantum fluctuations …