Emerging solid-state cycloaddition chemistry for molecular solar thermal energy storage

C Raju, HPQ Nguyen, GGD Han - Chemical Science, 2024 - pubs.rsc.org
Recently discovered designs of solid-state molecular solar thermal energy storage systems
are illustrated, including alkenes, imines, and anthracenes that undergo reversible [2+ 2] …

Pyrene-Functionalized Ru-Catenated Metallacycles: Conversion of Catenated System to Monorectangle through Aging

G Gupta, J Lee, R Hadiputra, J Jung… - Journal of the …, 2024 - ACS Publications
Molecular transformation behavior within a mechanically interlocked system is often assisted
by chemical manipulation, such as the inclusion of guest molecules, variation in the solution …

Multiple control of azoquinoline based molecular photoswitches

Y Lv, H Ye, L You - Chemical Science, 2024 - pubs.rsc.org
Multi-addressable molecular switches with high sophistication are creating intensive
interest, but are challenging to control. Herein, we incorporated ring–chain dynamic covalent …

Photocontrol of catalysis in CuAAC reactions by air stable Cu (i) complexes of phenylazopyrazole-incorporated ligands

D Gupta, AK Gaur, D Chauhan, SK Thakur… - Inorganic Chemistry …, 2024 - pubs.rsc.org
Metal complexes containing organic photoswitches are capable of modulating the steric and
electronic environment around the metal center through photoisomerization, enabling their …

Incorporating Photoresponses into Porous Liquids

MC Brand, HG Trowell, MJ Fuchter… - … –A European Journal, 2024 - Wiley Online Library
Porous liquids combine the properties of a porous solid with those of a liquid, creating a
porous flowable media. Since their discovery, these materials have gathered widespread …

Property Tuning in N‐Methylpyrrole Azo‐Photoswitches via Modification of the Peripheral Substituents

V Jelínková, A Dellai, L Verwaerde… - … A European Journal, 2025 - Wiley Online Library
Differently substituted pyrrole‐azo‑benzene molecular photoswitches were prepared in a
straightforward synthetic way. Their fundamental properties were investigated by XRD …

Neutral and ionic N-methyl phenylazo-3, 5-(di-2-pyridyl) pyrazole photoswitches: probes for reversible pH modulation by light

S Singh, A Velloth, M Goyal, N Kaur, S Singh… - Chemical …, 2024 - pubs.rsc.org
We report the design, synthesis, photoswitching and computational studies of N-methyl
arylazo-3, 5-(di-2-pyridyl) pyrazole and its N-alkyl pyridinium derivatives with an ionic center …

Azopyridinium Ionic Photoswitches: Tuning Half‐Lives of Z Isomers from Seconds to Days in Water

A Kumar Gaur, D Gupta… - … A European Journal, 2024 - Wiley Online Library
Herein, we describe water‐soluble heteroaryl azopyridinium ionic photoswitches (HAPIPs).
We aim to combine variations in five‐membered heterocycles, their substitutions, N‐alkyl …

N‐Aromatic Complexation in Tetraphenyl Porphyrin Iron (III)‐Pyridine: Evidence of Spin‐Flip via Gas‐Phase Electronic Spectroscopy

KO Uleanya, SA Wilson, CEH Dessent - ChemPhysChem, 2024 - Wiley Online Library
There is growing interest in the electronic properties of metalloporphyrins especially in
relation to their interactions with other molecular species in their local environment. Here …

Photoreactivity of C=N Double Bond Using N‐(4‐Pyridylmethylene)Aniline‐Coordinated Zn(II) Complex Crystal

Y Chen, Y Song, Y Saito, X Zheng… - European Journal of …, 2024 - Wiley Online Library
The photoirradiation to the Zn complex crystal having N‐(4‐pyridylmethylene) aniline (4‐
pma) ligand with a central–C= N‐bond led to no photodimerization reaction but only partial …