A decade update on solvent and catalyst-free neat organic reactions: a step forward towards sustainability

A Sarkar, S Santra, SK Kundu, A Hajra, GV Zyryanov… - Green …, 2016 - pubs.rsc.org
Particular success has been achieved in the synthesis of new products and in processes
since the twelve principles of “green chemistry” were formulated in the 1990s. These …

Olefination reactions of phosphorus-stabilized carbon nucleophiles

Y Gu, SK Tian - Stereoselective Alkene Synthesis, 2012 - Springer
Abstract A range of phosphorus-stabilized carbon nucleophiles have been employed for
alkene synthesis with high chemo-, regio-, and stereoselectivity. The Wittig, Horner …

Wittig Reactions in Water Media Employing Stabilized Ylides with Aldehydes. Synthesis of α,β-Unsaturated Esters from Mixing Aldehydes, α-Bromoesters, and Ph3P in Aqueous …

A El-Batta, C Jiang, W Zhao, R Anness… - The Journal of …, 2007 - ACS Publications
Water is demonstrated to be an effective medium for the Wittig reaction over a wide range of
stabilized ylides and aldehydes. Despite sometimes poor solubility of the reactants, good …

A facile synthesis and properties of multicarbazole molecules containing multiple vinylene bridges

JX Yang, XT Tao, CX Yuan, YX Yan… - Journal of the …, 2005 - ACS Publications
Multibranched π-conjugated materials and hyperbranched polymers have received
considerable interest in both academic research and industrial applications because of their …

High‐Energy Ball Milling Enables an Ultra‐fast Wittig Olefination Under Ambient and Solvent‐free Conditions

J Templ, M Schnürch - Angewandte Chemie International …, 2024 - Wiley Online Library
30 Seconds to success!–The Wittig reaction, a fundamental and extensively utilized reaction
in organic chemistry, enables the efficient conversion of carbonyl compounds to olefins …

Wittig-and Horner-Wadsworth-Emmons-olefination reactions with stabilised and semi-stabilised phosphoranes and phosphonates under non-classical conditions.

Y Al Jasem, R El-Esawi… - Journal of Chemical …, 2014 - search.ebscohost.com
Developments in the Wittig and Horner-Wadsworth-Emmons (HWE)-olefination of aldehydes
and ketones with stabilised phosphoranes or phosphonates provide opportunities for …

New and Facile Approach for the Synthesis of (E)‐α,β‐Unsaturated Esters and Ketones

BC Raju, P Suman - Chemistry–A European Journal, 2010 - infona.pl
A general and practical synthesis of (E)‐α, β‐unsaturated esters and ketones was achieved
by the reaction of carbonyl compounds with ethyl‐4, 4, 4‐trifluoroacetoacetate and trifluoro …

Ruthenium-Catalyzed Chemo-Selective Carbene Insertion into C–H Bond of Styrene over Cyclopropanation: C–C Bond Formation

A Jayarani, M Deepa, HA Khan… - The Journal of …, 2023 - ACS Publications
The C–C bond formation reactions are important in organic synthesis. Heck reaction is
known to arylate the terminal carbon of olefins; however, direct alkylation of the terminal …

Solvent-free horner–wadsworth–emmons reaction using DBU

K Ando, K Yamada - Tetrahedron Letters, 2010 - Elsevier
Solvent-free Horner–Wadsworth–Emmons reaction using DBU - ScienceDirect Skip to main
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Silica gel-mediated organic reactions under organic solvent-free conditions

S Onitsuka, YZ Jin, AC Shaikh, H Furuno, J Inanaga - Molecules, 2012 - mdpi.com
Silica gel was found to be an excellent medium for some useful organic transformations
under organic solvent-free conditions, such as (1) the Friedel-Crafts-type nitration of arenes …