Electronic properties of N-heterocyclic carbenes and their experimental determination

HV Huynh - Chemical reviews, 2018 - ACS Publications
N-Heterocyclic carbenes (NHCs) have become without doubt one of the most exciting and
popular species in chemical science due to the ease of their preparation and modularity in …

Mesoionic and related less heteroatom-stabilized N-heterocyclic carbene complexes: synthesis, catalysis, and other applications

A Vivancos, C Segarra, M Albrecht - Chemical reviews, 2018 - ACS Publications
Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …

Forever young: the first seventy years of ferrocene

P Štěpnička - Dalton Transactions, 2022 - pubs.rsc.org
The discovery of ferrocene,[Fe (η5-C5H5) 2], seventy years ago has significantly influenced
chemical research and provided a key impetus for establishing and rapidly expanding …

Chemistry of compounds based on 1, 2, 3-triazolylidene-type mesoionic carbenes

R Maity, B Sarkar - JACS au, 2021 - ACS Publications
Mesoionic carbenes (MICs) of the 1, 2, 3-triazolylidene type have established themselves as
a popular class of compounds over the past decade. Primary reasons for this popularity are …

Cooperative effects in multimetallic complexes applied in catalysis

R Maity, BS Birenheide, F Breher, B Sarkar - ChemCatChem, 2021 - Wiley Online Library
The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …

Redox-switchable ring-opening polymerization with ferrocene derivatives

J Wei, PL Diaconescu - Accounts of Chemical Research, 2019 - ACS Publications
Conspectus Switchable catalysts incorporate stimuli-responsive features and allow synthetic
tasks that are difficult or impossible to accomplish in other ways. They mimic biological …

Recent developments on artificial switchable catalysis

J Choudhury - Tetrahedron Letters, 2018 - Elsevier
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A redox-switchable gold (I) complex for the hydroamination of acetylenes: a convenient way for studying ligand-derived electronic effects

C Ruiz-Zambrana, M Poyatos, E Peris - ACS Catalysis, 2022 - ACS Publications
A gold complex with a naphthalene-di-imide-functionalized N-heterocyclic carbene (NHC)
ligand was prepared and characterized. The electrochemical studies reveal that the complex …

Rhenium Complexes of Pyridyl-Mesoionic Carbenes: Photochemical Properties and Electrocatalytic CO2 Reduction

L Suntrup, F Stein, J Klein, A Wilting… - Inorganic …, 2020 - ACS Publications
Mesoionic carbenes have found wide use as components of homogeneous catalysts.
Recent discoveries have, however, shown that metal complexes of such ligands also have …

Silver-Free Catalysis with Gold (I) Chloride Complexes

A Franchino, M Montesinos-Magraner… - Bulletin of the …, 2021 - academic.oup.com
Gold (I) chloride complexes are stable, widespread precatalysts that generally require
activation by halide abstraction to display useful catalytic activity. Chloride scavenging is …