The metal-hydride hydrogen atom transfer (MHAT) reaction plays an important role in the
field of natural product synthesis. MHAT, as a powerful method, has been employed by …

Sesquiterpene lactones, especially guaianolides representing a bigger class of natural
products, have served as appealing candidates for total synthesis due to their varied bio-and …

The α‐methylene‐γ‐butyrolactone motif is a widely encountered unit in many natural
products and pharmaceutical compounds. Herein, a practical and efficient synthesis of α …

A Co-catalyzed selective C–C bond cleavage followed by the silylperoxylation of alkene
substrates generated a series of alkylsilyl peroxides with good yields and selectivities …

The divergent synthesis of natural products is rapidly developing towards achieving the goal
of efficiency and economy in total synthesis. However, presently, the sustainable …

Metal-mediated cyclizations are important transformations in a natural product total
synthesis. The Pauson-Khand reaction, particularly powerful for establishing …

A divergent synthetic approach to six Ganoderma meroterpenoids, namely ganocins A–C,
ganocochlearins C and D, and cochlearol T, has been developed for the first time. This …

A concise and scalable asymmetric total synthesis of eupalinilde E from (R)-(−)-carvone in
12 steps is reported with an overall yield of 20%. The key steps of the synthesis are a …

The necessity for highly selective oxidative transformations towards the synthesis of complex
natural compounds such as sesquiterpenoids makes total synthesis a rich terrain of …

We describe a general strategy for the intermolecular synthesis of polysubstituted
cyclopentenones using palladium catalysis. Overall, this reaction is achieved via a …