Supramolecular coordination cages for artificial photosynthesis and synthetic photocatalysis

R Ham, CJ Nielsen, S Pullen, JNH Reek - Chemical Reviews, 2023 - ACS Publications
Because sunlight is the most abundant energy source on earth, it has huge potential for
practical applications ranging from sustainable energy supply to light driven chemistry. From …

Molecular cavity for catalysis and formation of metal nanoparticles for use in catalysis

R Saha, B Mondal, PS Mukherjee - Chemical Reviews, 2022 - ACS Publications
The employment of weak intermolecular interactions in supramolecular chemistry offers an
alternative approach to project artificial chemical environments like the active sites of …

Design and applications of water-soluble coordination cages

EG Percástegui, TK Ronson, JR Nitschke - Chemical Reviews, 2020 - ACS Publications
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …

Chemical reactivity under nanoconfinement

AB Grommet, M Feller, R Klajn - Nature nanotechnology, 2020 - nature.com
Confining molecules can fundamentally change their chemical and physical properties.
Confinement effects are considered instrumental at various stages of the origins of life, and …

Molecular barrels as potential hosts: from synthesis to applications

R Banerjee, D Chakraborty… - Journal of the American …, 2023 - ACS Publications
Self-assembled discrete molecular architectures that show selective molecular recognition
within their internal cavities are highly desirable. Such hosts often show guest recognition …

Picking the lock of coordination cage catalysis

TK Piskorz, V Martí-Centelles, RL Spicer, F Duarte… - Chemical …, 2023 - pubs.rsc.org
The design principles of metallo-organic assembly reactions have facilitated access to
hundreds of coordination cages of varying size and shape. Many of these assemblies …

Strategies for binding multiple guests in metal–organic cages

FJ Rizzuto, LKS von Krbek, JR Nitschke - Nature Reviews Chemistry, 2019 - nature.com
The binding of multiple guests by a single entity can lead to new modes of host–guest
interactions and thus new applications in, for example, catalysis and sensing. With the aim of …

Photochemistry and photophysics of MOFs: steps towards MOF-based sensing enhancements

EA Dolgopolova, AM Rice, CR Martin… - Chemical Society …, 2018 - pubs.rsc.org
In this review, we highlight how recent advances achieved in the fields of photochemistry
and photophysics of metal–organic frameworks (MOFs) could be applied towards the …

Supramolecular catalysis. Part 2: artificial enzyme mimics

M Raynal, P Ballester, A Vidal-Ferran… - Chemical Society …, 2014 - pubs.rsc.org
The design of artificial catalysts able to compete with the catalytic proficiency of enzymes is
an intense subject of research. Non-covalent interactions are thought to be involved in …

Supramolecular photochemistry as a potential synthetic tool: photocycloaddition

V Ramamurthy, J Sivaguru - Chemical reviews, 2016 - ACS Publications
Photochemistry, bearing significant applications in natural and man-made events such as
photosynthesis, vision, photolithography, photodynamic therapy, etc., is yet to become a …