Transmetalation of unsaturated carbon nucleophiles from boron-containing species to the mid to late d-block metals of relevance to catalytic C− X coupling reactions …
DV Partyka - Chemical Reviews, 2011 - ACS Publications
Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …
Rhenium (VII) oxo and imido complexes: synthesis, structures, and applications
CC Romão, FE Kühn, WA Herrmann - Chemical reviews, 1997 - ACS Publications
The first examples of organometallic derivatives of metal oxides appeared in a syncretic
fashion and were merely regarded as laboratory curiosities in a time where low oxidation …
fashion and were merely regarded as laboratory curiosities in a time where low oxidation …
Mechanism of Nitrogen-Carbon Bond Formation from Iron(IV) Disilylhydrazido Intermediates during N2 Reduction
We recently reported a reaction sequence that activates C–H bonds in simple arenes as well
as the N–N triple bond in N2, delivering the aryl group to N2 to form a new N–C bond …
as the N–N triple bond in N2, delivering the aryl group to N2 to form a new N–C bond …
Design and study of homogeneous catalysts for the selective, low temperature oxidation of hydrocarbons
BL Conley, WJ Tenn III, KJH Young, SK Ganesh… - Journal of Molecular …, 2006 - Elsevier
The direct, low temperature conversion of hydrocarbons to functionalized products using
novel, single site catalysts could lead to technological advances that redefine the landscape …
novel, single site catalysts could lead to technological advances that redefine the landscape …
CH Activation with an O-Donor Iridium− Methoxo Complex
WJ Tenn, KJH Young, G Bhalla, J Oxgaard… - Journal of the …, 2005 - ACS Publications
CH Activation with an O-Donor Iridium−Methoxo Complex | Journal of the American
Chemical Society ACS ACS Publications C&EN CAS Find my institution Log In Journal of …
Chemical Society ACS ACS Publications C&EN CAS Find my institution Log In Journal of …
Rhenium-catalyzed oxidation of thiols and disulfides with sulfoxides
JB Arterburn, MC Perry, SL Nelson… - Journal of the …, 1997 - ACS Publications
Oxidation reactions of organosulfur compounds hold continuing fascination for chemists
because of their fundamental roles in biochemical and industrial processes and the variety …
because of their fundamental roles in biochemical and industrial processes and the variety …
Kinetics and mechanisms of catalytic oxygen atom transfer with oxorhenium (V) oxazoline complexes
J Arias, CR Newlands, MM Abu-Omar - Inorganic Chemistry, 2001 - ACS Publications
The rhenium (V) monooxo complexes (hoz) 2Re (O) Cl (1) and [(hoz) 2Re (O)(OH2)][OTf](2)
have been synthesized and fully characterized (hoz= 2-(2 '-hydroxyphenyl)-2-oxazoline). A …
have been synthesized and fully characterized (hoz= 2-(2 '-hydroxyphenyl)-2-oxazoline). A …
C−N Bond Formation on Addition of Aryl Carbanions to the Electrophilic Nitrido Ligand in TpOs(N)Cl2
TJ Crevier, BK Bennett, JD Soper… - Journal of the …, 2001 - ACS Publications
The osmium (VI) nitrido complex TpOs (N) Cl2 (1) has been prepared from K [Os (N) O3] and
KTp in aqueous ethanolic HCl. It reacts rapidly with PhMgCl and related reagents with …
KTp in aqueous ethanolic HCl. It reacts rapidly with PhMgCl and related reagents with …
Activation of carbon–hydrogen bonds and dihydrogen by 1, 2-CH-addition across metal–heteroatom bonds
JR Webb, SA Burgess, TR Cundari, TB Gunnoe - Dalton Transactions, 2013 - pubs.rsc.org
The controlled conversion of hydrocarbons to functionalized products requires selective C–
H bond cleavage. This perspective provides an overview of 1, 2-CH-addition of …
H bond cleavage. This perspective provides an overview of 1, 2-CH-addition of …
Rare Examples of Fe(IV) Alkyl-Imide Migratory Insertions: Impact of FeC Covalency in (Me2IPr)Fe(NAd)R2 (R = neoPe, 1-nor)
BP Jacobs, PT Wolczanski, Q Jiang… - Journal of the …, 2017 - ACS Publications
The iron (IV) imide complexes,(Me2IPr)–R2Fe= NAd (R= neoPe (3a), 1-nor (3b)) undergo
migratory insertion to iron (II) amides (Me2IPr) RFe {NR (Ad)}(R= neoPe (4a), 1-nor (4b)) …
migratory insertion to iron (II) amides (Me2IPr) RFe {NR (Ad)}(R= neoPe (4a), 1-nor (4b)) …