Synthesis of biodegradable polymers: a review on the use of schiff-base metal complexes as catalysts for the ring opening polymerization (ROP) of cyclic esters

O Santoro, X Zhang, C Redshaw - Catalysts, 2020 - mdpi.com
This review describes the recent advances (from 2008 onwards) in the use of Schiff-base
metal complexes as catalysts for the ring opening polymerization (ROP) of cyclic esters. The …

Recent progress in the application of group 1, 2 & 13 metal complexes as catalysts for the ring opening polymerization of cyclic esters

J Gao, D Zhu, W Zhang, GA Solan, Y Ma… - Inorganic Chemistry …, 2019 - pubs.rsc.org
High performance biodegradable polymers (eg, aliphatic polyesters) that can display
properties that rival polyolefins are seen as future high demand materials for a variety of …

Simple and Efficient Zinc Catalysts for Synthesis and Chemical Degradation of Polyesters

F Santulli, D Pappalardo, M Lamberti… - ACS Sustainable …, 2023 - ACS Publications
A series of zinc complexes supported by tridentate imino-phenolate ligands with different
substituents on the phenolate ring and bearing a pyridyl ring as an additional coordinative …

Are Well Performing Catalysts for the Ring Opening Polymerization of l-Lactide under Mild Laboratory Conditions Suitable for the Industrial Process? The Case of …

MC D'Alterio, I D'Auria, L Gaeta, C Tedesco… - …, 2022 - ACS Publications
Poly (lactic acid)(PLA) is one of the best candidates as a sustainable plastic material for a
circular economy, being biodegradable, bio-based, recyclable, and displaying good thermal …

Homoleptic phenoxy-imine pyridine zinc complexes: efficient catalysts for solvent free synthesis and chemical degradation of polyesters

S D'Aniello, S Laviéville, F Santulli, M Simon… - Catalysis Science & …, 2022 - pubs.rsc.org
The synthesis and structural characterization of six homoleptic zinc complexes supported by
monoanionic phenoxy-imine pyridine ligands bearing different substituents on the phenoxy …

Zinc and magnesium catalysts for the synthesis for PLA and its degradation: Clues for catalyst design

F Santulli, G Gravina, M Lamberti, C Tedesco… - Molecular …, 2022 - Elsevier
Homoleptic and heteroleptic zinc and magnesium complexes bearing phenoxy-imine
pyridine ligands were synthetized and characterized. Several structural parameters such as …

[HTML][HTML] 开环聚合催化剂用于脂肪族聚酯合成的研究进展

张昊天, 胡晨阳, 李莉莉, 庞烜 - 高分子学报, 2022 - gfzxb.org
与广泛使用的聚烯烃材料相比, 脂肪族聚酯由于其独特的生物相容性和可降解性, 在电子,
包装和生物医学等领域都有广泛的应用. 开环聚合(ROP) 是目前合成脂肪族聚酯的主要方法 …

Guanidinate Zn (II) Complexes as Efficient Catalysts for Lactide Homo-and Copolymerization under Industrially Relevant Conditions

I D'Auria, V Ferrara, C Tedesco… - ACS Applied Polymer …, 2021 - ACS Publications
Poly (lactic acid)(PLA) is currently by far the most commercially relevant biodegradable
polymer derived from bio-renewable sources. The industrial production of high molecular …

Highly active homoleptic zinc and magnesium complexes supported by constrained reduced schiff base ligands for the ring-opening polymerization of lactide

T Pongpanit, T Saeteaw, P Chumsaeng… - Inorganic …, 2021 - ACS Publications
New homoleptic zinc and magnesium complexes containing constrained reduced Schiff
base ligands based on substituted 7-hydroxy-1-indanone were successfully synthesized …

Tailor-made block copolymers of l-, d-and rac-lactides and ε-caprolactone via one-pot sequential ring opening polymerization by pyridylamidozinc (ii) catalysts

I D'Auria, MC D'Alterio, C Tedesco, C Pellecchia - RSC advances, 2019 - pubs.rsc.org
Three-coordinated Zn (II) complexes bearing sterically encumbered bidentate monoanionic
[N, N−] pyridylamido ligands efficiently catalyze the ring opening polymerization of lactide …