Homo and Heteromultimetallic Complexes Containing a Group 8 Transition Metal and μ-diphosphine Bridging Ligands Involved in Anticancer Research: A Review

B Roufosse, C Serbu, C Marschner, S Prince… - European Journal of …, 2024 - Elsevier
Herein, we present a comprehensive review focusing on synthetic strategies, detailed
structural analysis, and anticancer activity investigations of complexes following the general …

Organometallic gas‐phase ion chemistry and catalysis: insights into the use of metal catalysts to promote selectivity in the reactions of carboxylic acids and their …

RAJ O'Hair - Mass spectrometry reviews, 2021 - Wiley Online Library
Carboxylic acids are valuable organic substrates as they are widely available, easy to
handle, and exhibit structural and functional variety. While they are used in many standard …

Synergistic Cu2 Catalysts for Formic Acid Dehydrogenation

T Nakajima, Y Kamiryo, M Kishimoto… - Journal of the …, 2019 - ACS Publications
Hexanuclear copper hydride complexes,[Cu6 (μ3-H) 2 (meso-L 4) 3 (RNC) 4](PF6) 4 (R= t
Bu (6a), Cy (6b)), were prepared by using a new linear tetraphosphine, meso-Ph2PCH2P …

Electronic spectroscopy of homo-and heterometallic binuclear coinage metal phosphine complexes in isolation

MJP Schmitt, SV Kruppa, SP Walg, WR Thiel… - Physical Chemistry …, 2023 - pubs.rsc.org
Binuclear coinage metal phosphine complexes are examined under ion trap isolation in
order to elucidate their noncovalent binding, structural properties and intrinsic electronic …

Synthesis and X‐Ray Crystallographic Characterisation of Frustum‐Shaped Ligated [Cu18H16(DPPE)6]2+ and [Cu16H14(DPPA)6]2+ Nanoclusters and Studies on Their …

J Li, HZ Ma, GE Reid, AJ Edwards… - … A European Journal, 2018 - Wiley Online Library
We report new structural motifs for Cu nanoclusters that conceptually represent seed crystals
for large face‐centred cubic (FCC) crystal growth. Kinetically controlled syntheses, high …

Formate dehydrogenase activity by a Cu (ii)-based molecular catalyst and deciphering the mechanism using DFT studies

A Mishra, D Srivastava, D Raj, N Patra… - Dalton Transactions, 2024 - pubs.rsc.org
Due to the requirement to establish renewable energy sources, formic acid (FA), one of the
most probable liquid organic hydrogen carriers (LOHCs), has received great attention …

Gas-Phase Ion–Molecule Reactions of Copper Hydride Anions [CuH2] and [Cu2H3]

A Zavras, H Ghari, A Ariafard, AJ Canty… - Inorganic …, 2017 - ACS Publications
Gas-phase reactivity of the copper hydride anions [CuH2]–and [Cu2H3]–toward a range of
neutral reagents has been examined via multistage mass spectrometry experiments in a …

Hexanuclear Copper (I) Hydride from the Reduction-Induced Decarboxylation of a Dicopper (II) Formate

J Lücken, T Auth, SI Mozzi, F Meyer - Inorganic Chemistry, 2020 - ACS Publications
Copper (I) hydride complexes represent a promising entry into formic acid dehydrogenation
catalysis. Herein we present the spontaneous decarboxylation of a μ1, 3-formate-bridged …

Solar-heating thermocatalytic H 2 production from formic acid by a MoS 2-graphene-nickel foam composite

X Bai, S Li, Y Zhang, S Zhu, L Gao, R Cong, W Yu… - Green …, 2021 - pubs.rsc.org
Sunlight driven formic acid decomposition has great potential to supply high-purity H2
without consuming fossil fuel-derived energy. However, a trace amount of CO invariably …

A dicopper platform that stabilizes the formation of pentanuclear coinage metal hydride complexes

AN Desnoyer, A Nicolay, MS Ziegler… - Angewandte Chemie …, 2020 - Wiley Online Library
Reduction of a dicopper (II) bis (hydroxide) complex with silanes in the presence of external
copper or silver cations results in the formation of multinuclear hydride clusters, which were …