This review sets out to understand the reactivity of diradicals and how that may differ from
monoradicals. In the first part of the review, we delineate the electronic structure of a …

Solid oxygen is a unique crystal combining properties of a simple molecular solid and of a
magnet. Unlike ordinary magnets, the exchange interaction in solid oxygen acts on a …

The collisions between two oxygen molecules give rise to O4 absorption in the Earth
atmosphere. O4 absorption is relevant to atmospheric transmission and Earth's radiation …

Experimental heats of formation and enthalpies obtained from G4 calculations both find that
the resonance stabilization of the two unpaired electrons in triplet O2, relative to the …

Peroxo/superoxo is a key intermediate in oxygen evolution/reduction reactions in (electro)
catalysis. However, peroxo/superoxo analogues have aroused controversies relevant to the …

Of the simple diatomic molecules, oxygen is the only one to carry a magnetic moment. This
makes solid oxygen particularly interesting: it is considered a 'spin-controlled'crystal that …

Molecular beam experiments are reported for collisions between oxygen molecules. Total
integral cross sections have been measured as a function of the collision energy with the …

We report a detailed experimental characterization of the infrared absorption properties of
the high pressure, red phase of oxygen. Spectra are measured in the far infrared, down to …

This article gives a perspective view of some representative experimental information
available on interatomic forces. They play a role in gaseous properties, but modern …

We present a global ground-state potential energy surface (PES) for the triplet spin state of O
4 that is suitable for treating high-energy vibrational–rotational energy transfer and collision …