Polyoxometalates (POMs): from electroactive clusters to energy materials
Polyoxometalates (POMs) represent a class of nanomaterials, which hold enormous
promise for a range of energy-related applications. Their promise is owing to their “special” …
promise for a range of energy-related applications. Their promise is owing to their “special” …
Artificial photosynthesis: opportunities and challenges of molecular catalysts
Molecular catalysis plays an essential role in both natural and artificial photosynthesis (AP).
However, the field of molecular catalysis for AP has gradually declined in recent years …
However, the field of molecular catalysis for AP has gradually declined in recent years …
Design of molecular water oxidation catalysts with earth-abundant metal ions
M Kondo, H Tatewaki, S Masaoka - Chemical Society Reviews, 2021 - pubs.rsc.org
The four-electron oxidation of water (2H2O→ O2+ 4H++ 4e−) is considered the main
bottleneck in artificial photosynthesis. In nature, this reaction is catalysed by a Mn4CaO5 …
bottleneck in artificial photosynthesis. In nature, this reaction is catalysed by a Mn4CaO5 …
Recent advances in polyoxometalate-catalyzed reactions
SS Wang, GY Yang - Chemical reviews, 2015 - ACS Publications
Polyoxometalates (POMs) are composed of cations and polyanion clusters 1 with structural
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …
diversity, in which the oxometal polyhedra of MOx (x= 5, 6) are the basic construction units …
[HTML][HTML] Artificial photosynthesis: molecular systems for catalytic water oxidation
The sustainable production of clean energy constitutes one of the most important scientific
challenges of the 21st century. Currently, the major part of the global energy supply is …
challenges of the 21st century. Currently, the major part of the global energy supply is …
Dynamic light scattering: a powerful tool for in situ nanoparticle sizing
Z Jia, J Li, L Gao, D Yang, A Kanaev - Colloids and Interfaces, 2023 - mdpi.com
Due to surface effects and quantum size effects, nanomaterials have properties that are
vastly different from those of bulk materials due to surface effects. The particle size …
vastly different from those of bulk materials due to surface effects. The particle size …
Hybrid polyoxometalate materials for photo (electro-) chemical applications
Polyoxometalate (POM) based supramolecular assemblies have received significant
attention over recent years because of their unique and diverse redox and photochemical …
attention over recent years because of their unique and diverse redox and photochemical …
Polyoxometalate-based nickel clusters as visible light-driven water oxidation catalysts
XB Han, YG Li, ZM Zhang, HQ Tan, Y Lu… - Journal of the …, 2015 - ACS Publications
Three new polyoxometalate (POM)-based polynuclear nickel clusters, Na24 [Ni12 (OH) 9
(CO3) 3 (PO4)(SiW9O34) 3]· 56H2O (1), Na25 [Ni13 (H2O) 3 (OH) 9 (PO4) 4 (SiW9O34) 3] …
(CO3) 3 (PO4)(SiW9O34) 3]· 56H2O (1), Na25 [Ni13 (H2O) 3 (OH) 9 (PO4) 4 (SiW9O34) 3] …
Polyoxometalate-based cobalt–phosphate molecular catalysts for visible light-driven water oxidation
A series of all-inorganic, abundant-metal-based, high-nuclearity cobalt–phosphate (Co–Pi)
molecular catalysts [{Co4 (OH) 3 (PO4)} 4 (SiW9O34) 4] 32–(1),[{Co4 (OH) 3 (PO4)} 4 …
molecular catalysts [{Co4 (OH) 3 (PO4)} 4 (SiW9O34) 4] 32–(1),[{Co4 (OH) 3 (PO4)} 4 …
Nickel complexes as molecular catalysts for water splitting and CO2 reduction
JW Wang, WJ Liu, DC Zhong, TB Lu - Coordination Chemistry Reviews, 2019 - Elsevier
One of the most appealing strategies to address the problems of global warming and energy
shortage is to develop clean and sustainable energy source. To this end, considerable …
shortage is to develop clean and sustainable energy source. To this end, considerable …