There has been a rapid expansion in the use of molecular magnets for both low-and ultra
low-temperature cooling applications in recent years, and here we review the chemical …

This review outlines recent advances in the design of 3d-, 4f-, and 3d–4f type magnetic
molecules for use as excellent cryogenic magnetic coolants based on the magnetocaloric …

Recent years have witnessed a terrific increase in the number of molecule-based materials
proposed as magnetic refrigerants for liquid-helium temperatures.[1–15] Refrigeration …

Reaction of Gd (OAc) 3· 4H2O, salicylaldehyde and CH3ONa in MeCN/MeOH affords
[Gd12Na6 (OAc) 25 (HCO2) 5 (CO3) 6 (H2O) 12]· 9H2O. 0.5 MeCN (1· 9H2O. 0.5 MeCN) …

Magnetic refrigerants with a large magnetocaloric effect (MCE) in a wide temperature range
and low magnetic ordering temperature (T o) in the sub-kelvin temperature region are not …

A robust, stable and processable family of mononuclear lanthanoid complexes based on
polyoxometalates (POMs) that exhibit single-molecule magnetic behavior is described here …

To deal with the shortage and high price of helium-3 resources, adiabatic demagnetization
refrigeration technology as an alternative to helium-3-based refrigeration technology has …

Two rarely seen 2D coordination polymers based on huge 36-metal pure lanthanide
clusters,{[Gd36 (NA) 36 (OH) 49 (O) 6 (NO3) 6 (N3) 3 (H2O) 20] Cl2· 28H2O} n (1) and …

Two unique 3D coordination polymers based on octahedral [Ln6](Ln= Gd (1), Dy (2))
clusters as nodes were synthesized, exhibiting a novel (3, 12)-connected topology with the …

This review article examines the impact of zero-dimensional compounds in the field of
magnetic refrigeration, 20 years after the modern age of molecular magnetism began. The …