Synthesis, Crystal Structure, and Hirshfeld Surface Analysis of Hexachloroplatinate and Tetraclorouranylate of 3-Carboxypyridinium—Halogen Bonds and π …

AP Novikov, MA Volkov, AV Safonov, MS Grigoriev - Crystals, 2022 - mdpi.com
This work aimed to synthesize new platinum and uranium compounds with nicotinic acid. In
this article we describe the synthesis of two new anionic complexes (HNic) 2 [PtCl6] and …

Novel synthesis methods of new imidazole-containing coordination compounds Tc (IV, V, VII)—reaction mechanism, Xrd and hirshfeld surface analysis

MA Volkov, AP Novikov, MS Grigoriev… - International Journal of …, 2022 - mdpi.com
In this work, we have proposed two new methods for the synthesis of [TcO2L4]+(where L=
imidazole (Im), methylimidazole (MeIm)) complexes using thiourea (Tu) and Sn (II) as the …

Cation Protonation Degree Influence on the Formation of Anion⋅⋅⋅ Anion and Other Non‐Valent Interactions in Guaninium Perrhenates and Pertechnetate

AP Novikov, KE German, AV Safonov… - …, 2022 - Wiley Online Library
Abstract H2Gua (ReO4) 2, HGuaReO4 and HGuaTcO4 were first obtained and structurally
characterized. Two types of anionic interactions were found in the structure with the twice …

New O-and NN-Bridging Complexes of Tc (V), the Role of the Nitrogen Atom Position in Aromatic Rings: Reaction Mechanism, Spectroscopy, DTA, XRD and Hirshfeld …

AP Novikov, MA Volkov - International Journal of Molecular Sciences, 2022 - mdpi.com
In this work, O-and NN-bridging complexes of technetium (V), previously known only for
rhenium, were obtained for the first time. Tc (V) complexes with pyridazine (pyd), 1, 2, 4 …

An oxalato-bridged dimetallic heptanuclear [K5IFe2III] complex anion with guanidinium as counter cation: Synthesis, crystal structure, Hirshfeld surface analysis and …

C Nde, A Bouraima, BN Ndosiri, IN Kamga, LS Pouamo… - Polyhedron, 2023 - Elsevier
An oxalato-bridged heterometallic heptanuclear [K 5 I Fe 2 III] hybrid salt,(CH 6 N 3)[K 5 (H 2
O) 4 Fe 2 (C 2 O 4) 6](1)(CH 6 N 3+= guanidinium cation) has been synthesized and …

Synthesis, crystal structure, magnetic properties and Hirshfeld surface analysis of two cobalt (II) complex anions templated by pyridinium-based cations

LDD Njiki, BN Ndosiri, AN Nana, A Bouraima… - Polyhedron, 2023 - Elsevier
Two organic–inorganic hybrid salts,(C 6 H 9 N 2) 2 [Co (C 2 O 4) 2]· H 2 O (1) and (C 5 H 7 N
2) 2 [Co (C 2 O 4) 2 (H 2 O) 2](2)(C 6 H 9 N 2+= 2-amino-3-methylpyridinium; C 5 H 7 N 2+ …

Direct Synthesis of C-Substituted [RC(O)CH2-CB11H11] Carborate Anions

VC Barra, E Bernhardt, S Fellinger, C Jenne… - Inorganics, 2024 - mdpi.com
A new synthetic method for the synthesis of C-substituted [RC (O) CH2-CB11H11]−
carborate anions has been developed. The reaction of [closo-B11H11] 2− with terminal …

[PDF][PDF] Synthesis, crystal structure and Hirshfeld surface analysis of N-(4-fluorophenyl)-N-isopropyl-2-(methylsulfonyl) acetamide

D Geetha, HG Anil Kumar, M Kumar… - Acta …, 2023 - journals.iucr.org
The synthesis and crystal structure of the title compound, C12H16FNO3S, which is related to
the herbicide flufenacet, are presented. The dihedral angle between the amide group and …

Novel Synthesis Methods of New Imidazole-Containing Coordination Compounds and Salts Tc (IV, V, VII)–Reaction Mechanism, XRD and Hirshfeld Surface Analysis

MA Volkov, AP Novikov, MS Grigoriev, AM Fedoseev… - 2022 - preprints.org
In this work, we have proposed two new methods for the synthesis of [TcO2L4]+(where L= im-
idazole (Im), methylimidazole (MeIm)) complexes using thiourea (Tu) and Sn (II) as reducing …