Transition-metal-catalyzed reactions have been studied since the very beginning of the past
century and represent a great success in organic chemistry, along with the birth and growth …

The rich legacy of arenediazonium salts in the synthesis of unsymmetrical biaryls, built
around the seminal works of Pschorr, Gomberg and Bachmann more than a century ago …

We report herein a simple, additive-and metal-free, photoinduced, dual C–H/C–X borylation
of chloro-, bromo-, and iodoarenes. The reaction produces 1, 2-and 1, 3-diborylarenes on …

A metal‐free, visible light‐induced [4+ 2] benzannulation of biaryldiazonium salts with
alkynes was developed. With eosin Y as photoredox catalyst, a variety of 9‐substituted or 9 …

By all measures, 1, 1, 1, 3, 3, 3-hexafluoropropan-2-ol (HFP) appears as a solvent with
properties at the extreme. Its combination of low nucleophilicity, high hydrogen bonding …

Photo (sensitized) cleavage of benzenediazonium salts as well as, when an electron-
donating substituent is present, of aryl chlorides, fluorides, mesylates, triflates, and …

This paper presents a general survey of the mechanisms involved in drug phototoxicity.
Moreover, a list of 174currently used clinical drugs inducing photosensitization is provided in …

The visible light excitation of areneazo-2-(2-nitro) propane· HCl salts generated the singlet
aryl cation that readily underwent aromatic SN1 reactions with a variety of nucleophiles. The …

The photochemistry of some fluorinated 7-amino-4-quinolone-3-carboxylic acids used in
therapy as antibacterials and known to be phototoxic has been investigated in water. All of …

The photolysis of a series of 4-X-benzenediazonium tetrafluoroborates is studied in MeCN.
Loss of nitrogen occurs from the singlet excited state with X= H, t-Bu, and NMe2 and leads to …