The predominant role of carboxylate esters in preparative free radical chemistry has been as
a substituent on alkenes, activating them toward attack by nucleophilic radicals, 1 or on …

Winner of the PROSE Award for Chemistry & Physics 2010 Acknowledging the very best in
professional and scholarly publishing, the annual PROSE Awards recognise publishers' and …

For quite some time, the chemistry of carbohydrate derivatives has been based essentially
on ionic processes. The glycosidation reaction, which constitutes a continuing challenge in …

This Perspective outlines work in the Crich group on the diastereoselective synthesis of the
so-called difficult classes of glycosidic bond: the 2-deoxy-β-glycopyranosides, the β …

Intraperitoneal adhesions (IAs) are a major complication arising from abdominal repair
surgeries, including hernia repair procedures. Herein, we fabricated a composite mesh …

The formation and stereoselective quenching of 1-mannopyranosyl radicals by a tributyltin
hydride-mediated intramolecular 1, 5-hydrogen abstraction sequence is described. A …

The catalytic coupling of oxetane, the symmetric isomer of propylene oxide, with carbon
disulfide has been investigated utilizing (salen) CrCl in the presence of various onium salts …

Hydrogel microparticles (HMPs) have been investigated widely for their use in tissue
engineering and drug delivery applications. However, translation of these highly tunable …

Deoxygenations of alcohols, ie, processes that replace a hydroxyl group with hydrogen at a
saturated carbon, find applications in both total synthesis and the systematic modifications of …

Five dinucleating ligands (1− 5) and one trinucleating ligand (6) incorporating 1, 5, 9-
triazacyclododecan-3-yloxy groups attached to an aromatic scaffold have been synthesized …