Medium-sized heterocycles are widespread among a spectrum of structurally intriguing and
biologically significant natural products and synthetic pharmaceuticals. Metal-catalyzed high …

Conspectus Optically active nitrogen-containing compounds have attracted substantial
attention due to their ubiquity in the cores of natural products and bioactive molecules …

The first enantioselective formal [5+ 4] cycloaddition is realized under palladium catalysis to
deliver benzofuran-fused nine-membered rings. These medium-sized heterocycles and …

Abstract The first catalytic formal [5+ 4] cycloaddition to prepare nine‐membered
heterocycles is presented. Under palladium catalysis, the reaction of N‐tosyl azadienes and …

Catalytic asymmetric 1, 3-dipolar cycloadditions of azomethine ylides have turned out to be
one of the most efficient methods for the preparation of enantioenriched pyrrolidines. The …

Medium-sized rings, including those embedded in bridged and fused bicyclic scaffolds, are
common core structures of myriad bioactive molecules. Among various synthetic strategies …

The pyrrolidine ring is a privileged structural motif in synthetic and medicinal chemisty. This
review aims to highlight the high versatility of the catalytic asymmetric 1, 3-dipolar …

The nine-membered ring-bearing bicyclo [5.2. 2] tetrahydrooxonines frameworks have
enantioselectively been constructed via a tandem [3+ 2] cycloaddition/Cope rearrangement …

Reported herein is an asymmetric [3+ 2] cycloaddition reaction of azomethine ylides with β‐
trifluoromethyl β, β‐disubstituted enones, a reaction which is enabled by a Ming‐Phos …

Bridged polycycles are privileged molecular skeletons with wide occurrence in bioactive
natural products and pharmaceuticals. Therefore, they have been the pursing target …